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Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
Wear protective gloves when administering first aid. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Do NOT induce vomiting. Refer for medical attention .
Chemical is highly corrosive and toxic. Inhalation causes severe burns of mucous membrane. Ingestion causes severe burns of mouth. Contact with eyes or skin causes severe burns. (USCG, 1999)
Keep unconscious victims warm and on their sides to avoid choking if vomiting occurs. Immediately initiate the following emergency procedures, continuing them as appropriate en route to the emergency medical facility. 1. Eye Exposure: Tissue destruction and blindness may result from exposure to concentrated solutions, vapors, mists or aerosols of bromine pentafluoride! Immediately but gently flush the eyes with large amounts of water for at least 15 min, occasionally lifting the upper and lower eyelids. 2. Skin exposure: Severe burns, skin corrosion, and absorption of toxic amounts may result! Immediately remove all contaminated clothing! Immediately and gently wash skin for at least 15 min. Use soap and water if skin is intact; use only water if skin is not intact. 3. Inhalation exposure: If vapors, mists, or aerosols of bromine pentafluoride are inhaled, move the victim to fresh air immediately. If the victim is not breathing, clean any chemical contamination from the victim's lips and perform cardiopulmonary resuscitation; if breathing is difficult, give oxygen. 4. Ingestion exposure: Take the following steps if several pentafluoride or a solution containing it is ingested: Do not induce vomiting. Have the victim rinse the contaminated mouth cavity several times with a fluid such as water. Immediately after rinsing, have the victim drink one cup (8 ox) of fluid and no more. Do not permit the victim to drink milk or carbonated beverages! Do not permit the victim to drink any fluid if more than 60 min have passed since initial ingestion.
If material involved in fire: Do not use water on material itself. Use dry chemical or carbon dioxide. Cool all affected containers with flooding quantities of water. If large quantities of combustibles are involved, use water in flooding quantities as spray and fog. Use water spray to knock-down vapors.
Special Hazards of Combustion Products: Toxic and irritating fumes of hydrogen fluoride and bromine may form in fires. Behavior in Fire: Containers may burst when exposed to heat of fire. (USCG, 1999)
In case of fire in the surroundings, use appropriate extinguishing media. NO hydrous agents. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. Combat fire from a sheltered position.
| HEALTH | 4 | Very short exposure could cause death or major residual injury (e.g. hydrogen cyanide, phosgene, methyl isocyanate, hydrofluoric acid) | |
| FIRE | 0 | Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride) | |
| REACT | 3 | Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked (e.g. ammonium nitrate, cesium, hydrogen peroxide) | |
| SPEC. HAZ. | Oxidizer, allows chemicals to burn without an air supply (e.g. potassium perchlorate, ammonium nitrate,hydrogen peroxide). Reacts with water in an unusual or dangerous manner(e.g. caesium, sodium, sulfuric acid). |
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in vermiculite, earth, dry sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. Do NOT absorb in saw-dust or other combustible absorbents. NEVER direct water jet on liquid.
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in vermiculite, earth, dry sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. Do NOT absorb in saw-dust or other combustible absorbents. NEVER direct water jet on liquid.
Isolate the area until the release is under full control. Use water spray to cool and disperse vapors and protect personnel.
NO contact with flammables. NO contact with water, combustible substances or organic materials. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from food and feedstuffs and all other substances. See Chemical Dangers. Dry. Well closed. Keep in a well-ventilated room.Separate from acids, alkalies, halogens, salts, metals, organic matter. Store in a cool, dry, well-ventilated location. Keep cylinders restrained ...
TLV: 0.1 ppm as TWA
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use closed system or ventilation.
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Liquid
Pungent odor
-62.5°C
40,3°C
Noncombustible Liquid, but a very powerful oxidizer.
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Reacts with water violently (NIOSH, 2016)
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328 mm Hg (NIOSH, 2016)
2.48 g/cm3
6.05 (Air = 1)
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Decomposes above 460°C . Decomposes on contact with acids or acid fumes. This produces very toxic fumes of hydrogen fluoride(see ICSC 0283) and hydrogen bromide(see ICSC 0282). Reacts with fuels and organic compounds. This generates fire and explosion hazard. Reacts with water and steam. This produces toxic and corrosive fumes of hydrogen fluoride and hydrogen bromide. Reacts with all known elements, except nitrogen, oxygen and rare gases.
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Not combustible ...The vapour is heavier than air.BROMINE PENTAFLUORIDE an oxidizing agent. Is decomposed exothermically by water to hydrofluoric acid and other materials. Reacts with these other hydrogen-containing substances (among others) vigorously enough to cause a fire or explosion: acetic acid, ammonia, benzene, ethanol, hydrogen, hydrogen sulfide, methane, cork, grease paper, wax. Mixtures with acids, halogens, metal halides, metals, nonmetals, or metal oxides at ambient or slightly above ambient temperatures have resulted in violent reaction (nitric acid, sulfuric acid, chlorine, iodine, ammonium chloride, potassium iodide, boron powder, selenium, tellurium, aluminum powder, bismuth, cobalt powder, iron powder, arsenic, nickel powder, chromium trioxide, charcoal, red phosphorus, sulfur dioxide, magnesium oxide. Solutions of acetonitrile and 9% bromine pentafluoride have been found to decompose violently at ambient temperatures. Mixtures of perchloryl perchlorate and bromine pentafluoride form shock sensitive explosives. [Bretherick, 5th ed., 1995, p. 640].
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Acids, halogens, arsenic, selenium, sulfur, glass, organic materials, water [Note: Reacts with all elements except inert gases, nitrogen and oxygen.]
If involved in a fire decomposes to produce toxic gases.
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The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema. See Notes. Exposure could cause death.
May cause fluorosis due to formation of hydrogen fluoride. Further see ICSC 0283.
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.
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Bromine pentafluoride decomposes, sometimes explosively, on contact with water to yield hydrofluoric acid and other materials(1). Therefore, bioconcentration in fish is not expected to be an important fate process(SRC).
Bromine pentafluoride decomposes, sometimes explosively, on contact with water(1). It also explodes or ignites on contact with hydrogen-containing materials (e.g. acetic acid, ammonia, benzene, ethanol, hydrogen, hydrogen sulfide, methane cork, grease, paper, wax)(2).
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1745 (For reference only, please check.)
IMDG: UN1745 (For reference only, please check.)
IATA: UN1745 (For reference only, please check.)
ADR/RID: BROMINE PENTAFLUORIDE (For reference only, please check.)
IMDG: BROMINE PENTAFLUORIDE (For reference only, please check.)
IATA: BROMINE PENTAFLUORIDE (For reference only, please check.)
ADR/RID: 5.1 (For reference only, please check.)
IMDG: 5.1 (For reference only, please check.)
IATA: 5.1 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
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Reacts violently with fire extinguishing agents such as water.Depending on the degree of exposure, periodic medical examination is suggested.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.Do NOT take working clothes home.
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.