| Identification | More | [Name]
2-METHYL 4-BENZYLOXYBENZALDEHYDE | [CAS]
101093-56-5 | [Synonyms]
4-Benzyloxy-o-tolualdehyde
2-METHYL 4-BENZYLOXYBENZALDEHYDE
4-BENZYLOXY-2-METHYL-BENZALDEHYDE
2-methyl-4-phenylmethoxybenzaldehyde
Benzaldehyde,2-Methyl-4-(phenylMethoxy)- | [Molecular Formula]
C15H14O2 | [MDL Number]
MFCD01317809 | [Molecular Weight]
226.27 | [MOL File]
101093-56-5.mol |
| Chemical Properties | Back Directory | [Melting point ]
58.0 to 62.0 °C | [Boiling point ]
234°C/19mmHg(lit.) | [density ]
1.119±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Inert atmosphere,2-8°C | [form ]
powder to crystal | [color ]
White to Almost white | [InChI]
1S/C15H14O2/c1-12-9-15(8-7-14(12)10-16)17-11-13-5-3-2-4-6-13/h2-10H,11H2,1H3 | [InChIKey]
OGVPJBJWJCZBTH-UHFFFAOYSA-N | [SMILES]
Cc1cc(OCc2ccccc2)ccc1C=O | [CAS DataBase Reference]
101093-56-5(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Synthesis]
4-Hydroxy-2-methylbenzaldehyde (2.72 g, 19.98 mmol, 1.00 eq.) and benzyl bromide (3.8 g, 22.22 mmol, 1.11 eq.) were mixed with potassium carbonate (4.14 g, 29.95 mmol, 1.50 eq.) in acetonitrile (30 mL). The reaction mixture was stirred at room temperature for 3 hours. After completion of the reaction, water was added and extracted three times with ethyl acetate (EtOAc). The organic layers were combined, concentrated and purified by silica gel column chromatography (eluent ratio 10:1 petroleum ether/ethyl acetate) to afford 2-methyl-4-benzyloxybenzaldehyde (3.4 g, 75% yield) as a white solid. | [References]
[1] Patent: US2014/256657, 2014, A1. Location in patent: Paragraph 0297 |
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