| Identification | More | [Name]
4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL | [CAS]
1016-58-6 | [Synonyms]
4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL
6-NITROVERATRYL ALCOHOL
LABOTEST-BB LT00847721
RARECHEM AL BD 0187
TIMTEC-BB SBB009964
4,5-Dimethoxy-2-nitrobenzyl alcohol 98%
6-NITROVERATRYL ALCOHOL 98+%
4,5-Dimethoxy-2-nitrobenzyl alcohol, 98+%
2-Nitro-4,5-dimethoxybenzenemethanol
2-Nitro-4,5-dimethoxybenzyl alcohol
4,5-Dimethoxy-2-nitrobenzenemethanol
(4,5-Dimethoxy-2-nitro-phenyl)-methanol | [EINECS(EC#)]
213-806-4 | [Molecular Formula]
C9H11NO5 | [MDL Number]
MFCD00014701 | [Molecular Weight]
213.19 | [MOL File]
1016-58-6.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
145-148 °C (lit.) | [Boiling point ]
383.9±37.0 °C(Predicted) | [density ]
1.307±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
powder to crystal | [pka]
13.59±0.10(Predicted) | [color ]
White to Yellow to Green | [Water Solubility ]
Soluble in water. | [Sensitive ]
Light Sensitive | [λmax]
400nm(CH3CN)(lit.) | [BRN ]
1880093 | [CAS DataBase Reference]
1016-58-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [F ]
8 | [HazardClass ]
IRRITANT | [HS Code ]
29094990 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
4,5-Dimethoxy-2-nitrobenzyl alcohol (6-nitroveratryl alcohol) is suitable reagent used in the synthesis of 4,5-dimethoxy-2-nitrobenzyl methacrylate, a photolabile monomer and 2-(4-((4-(4,5-dimethoxy-2-nitrobenzyloxy)phenyl)cyclohexylidene)methyl)phenoxy)-N,N-dimethylethanamine, a caged cyclofen-OH ligand.
It may be used in the synthesis of the following:
- 1-[[(chlorocarbonyl)oxy]methyl]-4,5-dimethoxy-2-nitrobenzene
- bis(4,5-dimethoxy-2-nitrophenyl)ethylene glycol, a photolabile protecting group
- optically-sensitive monomer
- nitroveratryl (NV) protected α-hydroxyacetic acid (αG) (NV-αG-OH), required in the preparation of nitroveratryl (NV) protected cyanomethyl (CM) ester of α-hydroxyacetic acid (αG) (NV-αG-CM)
- 4,5-dimethoxy-2-nitrobenzyl p-nitro-phenylcarbonate
- 6-nitroveratryloxycarbonyl chloride (NVOCCl), a reagent used in the protection of amino function in amino sugars
| [Uses]
4,5-Dimethoxy-2-nitrobenzyl alcohol, is used as Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis. It is also used as photochemical protecting groups in organic synthesis. It is also used as a pharmaceutical intermediate. | [General Description]
4,5-Dimethoxy-2-nitrobenzyl alcohol (6-Nitroveratryl Alcohol) is 2-nitrobenzyl alcohol derivative. It has been reported to be one of the oxidation products of veratryl (3,4-dimethoxybenzyl) alcohol by lignin peroxidase (isolated from Phanerochaete chrysosporium). |
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