| Identification | More | [Name]
1,3-Diphenylguanidine | [CAS]
102-06-7 | [Synonyms]
1,3-DIPHENYLGUANIDINE
AURORA 2475
DIPHENYLGUANIDINE
DIPHENYLGUANIDINE-1,3
DPG
MELANILINE
N,N'-DIPHENYLGUANIDINE
SYM-DIPHENYLGUANIDINE
TIMTEC-BB SBB000514
VANAX DPG
1,3-Difenylguanid
1,3-diphenyl-guanidin
Accelerator D
AcceleratorD
Akrochem DPG
Denax
denaxdpg
DFG
DPG accelerator
dpgaccelerator | [EINECS(EC#)]
203-002-1 | [Molecular Formula]
C13H13N3 | [MDL Number]
MFCD00001758 | [Molecular Weight]
211.26 | [MOL File]
102-06-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white or cream powder with a slight odour | [Melting point ]
146-148 °C(lit.)
| [Boiling point ]
170°C | [density ]
1,13 g/cm3 | [vapor pressure ]
0Pa at 25℃ | [refractive index ]
1.6000 (estimate) | [Fp ]
170°C | [storage temp. ]
Store below +30°C. | [solubility ]
Soluble in alcohol, chloroform, hot benzene, hot toluene, and dilute mineral acids | [form ]
Powder | [pka]
pK1:10.12 (25°C) | [color ]
Pale Cream | [Odor]
wh. powd., bitter taste, sl. odor | [PH]
10.2 (10g/l, H2O) | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. Moisture sensitive. | [Water Solubility ]
slightly soluble | [Merck ]
14,3324 | [BRN ]
1875653 | [Henry's Law Constant]
1.4×106 mol/(m3Pa) at 25℃, HSDB (2015) | [Major Application]
cleaning products
cosmetics
food and beverages
personal care | [InChI]
1S/C13H13N3/c14-13(15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H,(H3,14,15,16) | [Contact allergens]
Diphenylguanidine is a rubber sensitizer that can induce immediate-type reactions and delayed-type contact allergy. It was formerly contained in “carba mix.” Occupational exposure concerns finished rubber items and the rubber manufacturing industry. The most frequent occupational categories are metal industry, homemakers, health services and laboratories, and the building industry. | [InChIKey]
OWRCNXZUPFZXOS-UHFFFAOYSA-N | [SMILES]
N=C(Nc1ccccc1)Nc2ccccc2 | [LogP]
2.42 at 21.1℃ | [CAS DataBase Reference]
102-06-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Guanidine, n,n'-diphenyl-(102-06-7) | [EPA Substance Registry System]
102-06-7(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
white or cream powder with a slight odour | [General Description]
White to cream-colored chalky powder. Bitter taste and slight odor. | [Reactivity Profile]
1,3-DIPHENYLGUANIDINE(102-06-7) behaves as an amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. This chemical is incompatible with strong oxidizers. | [Air & Water Reactions]
Sensitive to moisture. Aqueous solutions are strongly alkaline. Insoluble in water. | [Fire Hazard]
This chemical is combustible. | [Description]
Diphenylguanidine is a rubber sensitizer which can
induce immediate-type reactions and delayed-type contact allergy. It was formerly contained in "carbamix".
Occupational exposure concerns finished rubber
items and the rubber manufacturing industry. The
most frequent occupational categories are metal industry,
homemakers, health services and laboratories,
and building industries.
| [Uses]
1,3-Diphenylguanidine is used as pharmaceutical intermediate. | [Uses]
N,N'-Diphenylguanidine is a primary standard for acids; aeeelerator for the vulcanization of rubber for use with thiazoles and sulfenamides; complexing agent
in the deteetion of metals and organie bases. | [Definition]
ChEBI: 1,3-diphenylguanidine is guanidine carrying a phenyl substituent on each of the two amino groups. It is used as an accelerator in the rubber industry. It has a role as an allergen. | [Flammability and Explosibility]
Nonflammable | [Purification Methods]
1,3-Diphenylguanidine [102-06-7] M 211.3, m 148o, 10.12. Crystallise it from toluene, |
| Safety Data | Back Directory | [Symbol(GHS) ]
  
GHS06,GHS08,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H301-H315-H319-H335-H361f-H411 | [Precautionary statements ]
P202-P261-P273-P301+P310-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xn,N | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R62:Possible risk of impaired fertility. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 9/PG 3
| [WGK Germany ]
2
| [RTECS ]
MF0875000
| [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29252000 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral
Aquatic Chronic 2
Eye Irrit. 2
Repr. 2
Skin Irrit. 2
STOT SE 3 | [Safety Profile]
Poison by ingestion and
intraperitoneal routes. Experimental
teratogenic and reproductive effects.
Mutation data reported. When heated to
decomposition it emits toxic fumes of NOx,. | [Hazardous Substances Data]
102-06-7(Hazardous Substances Data) | [Toxicity]
LD50 oral in rabbit: 250mg/kg |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
China Langchem Inc.
|
| Telephone: |
0086-21-58956006 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
| Company Name: |
RYSS TECH LTD
|
| Telephone: |
400-188-0725 +86 21 34310725 13611771617 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15256/0_EN.htm |
| Company Name: |
Maya High Purity Chemicals
|
| Telephone: |
+86 (573) 82222445 (0)18006601000 452520369 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
|