102089-74-7

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102089-74-7 Structure

Identification	More
[Name] (R)-N-(tert-Butoxycarbonyl)-2-phenylglycinol
[CAS] 102089-74-7
[Synonyms] BOC-D-PHENYLGLYCINOL BOC-D-PHG-OL CARBAMIC ACID, [(1R)-2-HYDROXY-1-PHENYLETHYL]-, 1,1-DIMETHYLETHYL ESTER N-ALPHA-T-BOC-D-PHENYLGLYCINOL (-)-N-BOC-D-ALPHA-PHENYLGLYCINOL N-BOC-D-PHENYLGLYCINOL N-T-BOC-D-PHENYLGLYCINOL N-T-BUTOXYCARBONYL-D-PHENYLGLYCINOL R(-)-2-(BOC-AMINO)-2-PHENYLETHANOL (R)-(-)-N-BOC-2-PHENYLGLYCINOL (R)-N-BOC-2-PHENYLGLYCINOL (R)-(-)-N-(TERT-BUTOXYCARBONYL)-2-PHENYLGLYCINOL (R)-N-(TERT-BUTOXYCARBONYL)-2-PHENYLGLYCINOL (R)-N-(TERT-BUTOXYCARBONYL)-PHENYGLYCINOL N-Boc-R-penylglycinol Boc-D-Alpha-Phenylglycinol (R)-(-)-N-(TERT-BUTOXYCARBONYL)-2-PHENYL GLYCINOL, 99% (99% EE/GLC) N-BOC-R-PHENYLGLYCINOL N-Boc-D-2-phenylglycinol NALPHA-tert-Butoxycarbonyl-D-phenylglycinol
[EINECS(EC#)] 600-273-1
[Molecular Formula] C13H19NO3
[MDL Number] MFCD00274205
[Molecular Weight] 237.29
[MOL File] 102089-74-7.mol

Chemical Properties	Back Directory
[Appearance] white to light yellow crystal powde
[Melting point ] 137-139 °C(lit.)
[alpha ] -38°(19℃, c=1, CHCl3)
[Boiling point ] 382.4±35.0 °C(Predicted)
[density ] 1.101±0.06 g/cm3(Predicted)
[vapor pressure ] 0-70Pa at 20-50℃
[storage temp. ] Sealed in dry,Room Temperature
[solubility ] DMSO (Slightly), Methanol (Slightly)
[form ] Solid
[pka] 11.55±0.46(Predicted)
[color ] White to Off-White
[Optical Rotation] [α]19/D 38°, c = 1 in chloroform
[BRN ] 4688248
[Major Application] peptide synthesis
[InChI] InChI=1S/C13H19NO3/c1-13(2,3)17-12(16)14-11(9-15)10-7-5-4-6-8-10/h4-8,11,15H,9H2,1-3H3,(H,14,16)/t11-/m0/s1
[InChIKey] IBDIOGYTZBKRGI-NSHDSACASA-N
[SMILES] C(OC(C)(C)C)(=O)N[C@H](C1=CC=CC=C1)CO
[LogP] 1.59
[CAS DataBase Reference] 102089-74-7(CAS DataBase Reference)

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H315-H319-H335
[Precautionary statements ] P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362+P364-P403+P233-P501c
[Hazard Codes ] Xi
[Risk Statements ] R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ] S22:Do not breathe dust . S24/25:Avoid contact with skin and eyes . S25:Avoid contact with eyes . S24:Avoid contact with skin .
[WGK Germany ] 3
[REACH Registrations] Active
[HS Code ] 29051990
[Storage Class] 11 - Combustible Solids

Hazard Information	Back Directory
[Chemical Properties] white to light yellow crystal powde
[Uses] Chiral building block
[reaction suitability] reaction type: Boc solid-phase peptide synthesis

Spectrum Detail	Back Directory
[Spectrum Detail] (R)-N-(tert-Butoxycarbonyl)-2-phenylglycinol(102089-74-7)¹HNMR (R)-N-(tert-Butoxycarbonyl)-2-phenylglycinol(102089-74-7)IR

Well-known Reagent Company Product Information	Back Directory
[Acros Organics] (R)-(-)-N-BOC-2-phenylglycinol, 98%(102089-74-7)
[Alfa Aesar] N-Boc-D-alpha-phenylglycinol, 99%(102089-74-7)
[Sigma Aldrich] 102089-74-7(sigmaaldrich)

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