| Identification | Back Directory | [Name]
Dicyclohexyl(2,2-diphenyl-1-methylcyclopropyl)phosphine Cy-cBRIDP | [CAS]
1023330-38-2 | [Synonyms]
Cy-cBRIDP[R] Cy-cBRIDP 97% Cy-cBRIDP(regR) Cy-cBRIDP® Dicyclohexyl(2,2-diphenyl-1-methylcyclopropyl)phosphine Dicyclohexyl(2,2-diphenyl-1-methylcyclopropyl)phosphine Cy-cBRIDP | [Molecular Formula]
C28H37P | [MDL Number]
MFCD10565626 | [MOL File]
1023330-38-2.mol | [Molecular Weight]
404.57 |
| Chemical Properties | Back Directory | [Melting point ]
115-122°C | [storage temp. ]
2-8°C | [form ]
solid | [color ]
white to pale yellow | [Sensitive ]
air sensitive, store cold | [InChI]
1S/C28H37P/c1-27(29(25-18-10-4-11-19-25)26-20-12-5-13-21-26)22-28(27,23-14-6-2-7-15-23)24-16-8-3-9-17-24/h2-3,6-9,14-17,25-26H,4-5,10-13,18-22H2,1H3 | [InChIKey]
JDNAVZKVTWHWKB-UHFFFAOYSA-N | [SMILES]
CC1(CC1(c2ccccc2)c3ccccc3)P(C4CCCCC4)C5CCCCC5 | [CAS DataBase Reference]
1023330-38-2 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, BuchwaldHartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
- Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
- Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction.
|
| Hazard Information | Back Directory | [Uses]
Takasago Ligands and Complexes for Asymmetric Reactions | [Uses]
Dicyclohexyl(2,2-diphenyl-1-methylcyclopropyl)phosphine can be used as a catalyst. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand |
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