ChemicalBook--->CAS DataBase List--->742103-27-1

742103-27-1

742103-27-1 Structure

742103-27-1 Structure
IdentificationBack Directory
[Name]

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
[CAS]

742103-27-1
[Synonyms]

Mo-Phos
cBRIDP[R]
cBRIDP(regR)
cBRIDP®
Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-
[Molecular Formula]

C24H33P
[MDL Number]

MFCD09753012
[MOL File]

742103-27-1.mol
[Molecular Weight]

352.499
Chemical PropertiesBack Directory
[Melting point ]

87-91°C
[Boiling point ]

427.3±45.0 °C(Predicted)
[form ]

solid
[color ]

white to pale yellow
[Sensitive ]

air sensitive, store cold
[CAS DataBase Reference]

742103-27-1
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H335-H302+H312+H332-H315
[Precautionary statements ]

P280-P301+P312-P362+P364
[WGK Germany ]

3
[HS Code ]

2931499090
Questions And AnswerBack Directory
[Reactions]

  1. Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
  2. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
  3. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. 
Reactions of 742103-27-1
Hazard InformationBack Directory
[Uses]

Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.
[General Description]

This product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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