742103-27-1

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742103-27-1 Structure

Identification	Back Directory
[Name] Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
[CAS] 742103-27-1
[Synonyms] Mo-Phos cBRIDP[R] cBRIDP(regR) cBRIDP^{® Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-}
[Molecular Formula] C24H33P
[MDL Number] MFCD09753012
[MOL File] 742103-27-1.mol
[Molecular Weight] 352.499

Chemical Properties	Back Directory
[Melting point ] 87-91°C
[Boiling point ] 427.3±45.0 °C(Predicted)
[form ] solid
[color ] white to pale yellow
[Sensitive ] air sensitive, store cold
[CAS DataBase Reference] 742103-27-1

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H319-H335-H302+H312+H332-H315
[Precautionary statements ] P280-P301+P312-P362+P364
[WGK Germany ] 3
[HS Code ] 2931499090

Questions And Answer	Back Directory
[Reactions] Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction.

Hazard Information	Back Directory
[Uses] Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.
[General Description] This product has been enhanced for catalytic efficiency. A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.
[reaction suitability] reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand

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