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102390-98-7

102390-98-7 Structure

102390-98-7 Structure
IdentificationBack Directory
[Name]

NONAFLUOROHEXYLTRIETHOXYSILANE
[CAS]

102390-98-7
[Synonyms]

NONAFLUOROHEXYLTRIETHOXYSILANE
1H,1H,2H,2H-PERFLUOROHEXYLTRIETHOXYSILANE
1H,1H,2H,2H-Nonafluorohexyltriethoxysilane
Triethoxy(1H,1H,2H,2H-perfluorohexyl)silane
Triethoxy(1H,1H,2H,2H-nonafluorohexyl)silane
Silane,triethoxy(3,3,4,4,5,5,6,6,6-nonafluorohexyl)-
Triethoxy(1H,1H,2H,2H-nonafluorohexyl)silane
1H,1H,2H,2H-Nonafluorohexyltriethoxysilane Triethoxy(1H,1H,2H,2H-perfluorohexyl)silane
[Molecular Formula]

C12H19F9O3Si
[MDL Number]

MFCD09954454
[MOL File]

102390-98-7.mol
[Molecular Weight]

410.35
Chemical PropertiesBack Directory
[Boiling point ]

241.5±40.0 °C(Predicted)
[density ]

1.240±0.06 g/cm3(Predicted)
[refractive index ]

1.3470 to 1.3510
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.201
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[InChI]

InChI=1S/C12H19F9O3Si/c1-4-22-25(23-5-2,24-6-3)8-7-9(13,14)10(15,16)11(17,18)12(19,20)21/h4-8H2,1-3H3
[InChIKey]

NYIKUOULKCEZDO-UHFFFAOYSA-N
[SMILES]

[Si](OCC)(OCC)(OCC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)F
[EPA Substance Registry System]

Triethoxy(1,1,2,2,3,3,6,6,6-nonafluorohexyl)silane (102390-98-7)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H315-H319
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[TSCA ]

Yes
[HS Code ]

2931.90.9010
Hazard InformationBack Directory
[Chemical Properties]

Colorless transparent liquid.
[Uses]

Nonafluorohexyltriethoxysilane is an organic silane, which can be used as an organic reagent.
[Application]

Main applications of Nonafluorohexyltriethoxysilane
1) Used as a coupling agent to increase the bonding strength of the fluorine-containing resin and the substrate.
2) Used to prepare water-proof, oil-proof and anti-fouling treatment agents, and it can be used in the protection of water-proof, anti-fouling and weathering of cultural relics, masonry, metal, wood, etc.
3) Used as a finishing agent to reduce the water holding capacity of natural fiber (wool, cotton, leather, etc.) products, and to improve surface water repellency and stain resistance.
4) Used as a water-repellent and antifouling treatment on the surface of glass.
[Production Methods]

Nonafluorobutyl iodide (NFBI) and triethoxyvinylsilane (TEOVS) were fed into a three-necked flask equipped with a reflux condenser at a molar ratio of 1: 1.1 and then heated to 60 ℃ with stirring. When the internal temperature of the flask was sufficiently heated, azobisbutylnitrile (AIBN), a thermal decomposition radical initiator, was dissolved in an ether-based solvent. Then 0.5 ml/sec was dropped slowly into the stirred flask. After that, when the dropwise addition was completed, the external heating temperature was again set to 60 ℃ and stirred for 6 hours. After that, the internal temperature of the flask was lowered to room temperature (25 ℃), and tributyltin hydride (TBTH) was added to the flask at a rate of 1 ml/sec. After further stirring for 4 hours, distillation under reduced pressure at 1 Torr and 40 ° C yielded Nonafluorohexyltriethoxysilane in 75% yield.
Nonafluorohexyltriethoxysilane
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