| Identification | Back Directory | [Name]
N-(2-Methoxyphenyl)-2-(di-t-butylphosphino)pyrrole,92% [cataCXiuM POMetB] | [CAS]
1053658-91-5 | [Synonyms]
POMetB
N-(2-Methoxyphenyl)-2-(di-tert-butylphosphino)pyrrole
ditert-butyl-[1-(2-methoxyphenyl)pyrrol-2-yl]phosphane
N-(2-Methoxyphenyl)-2-(di-t-butylphosphino)pyrrole,92% [cataCXiuM POMetB]
N-(2-Methoxyphenyl)-2-(di-t-butylphosphino)pyrrole, min. 95% [cataCXium(R) POMetB] | [Molecular Formula]
C19H28NOP | [MDL Number]
MFCD06798301 | [MOL File]
1053658-91-5.mol | [Molecular Weight]
317.405 |
| Chemical Properties | Back Directory | [Boiling point ]
424.4±25.0 °C(Predicted) | [storage temp. ]
2-8°C, stored under nitrogen | [form ]
Powder | [pka]
-6.46±0.70(Predicted) | [color ]
white to yellowish | [Sensitive ]
air sensitive | [InChI]
1S/C19H28NOP/c1-18(2,3)22(19(4,5)6)17-13-10-14-20(17)15-11-8-9-12-16(15)21-7/h8-14H,1-7H3 | [InChIKey]
JALZQSOGOMZLEK-UHFFFAOYSA-N | [SMILES]
COc1ccccc1-n2cccc2P(C(C)(C)C)C(C)(C)C |
| Hazard Information | Back Directory | [Chemical Properties]
White to yellow powder | [General Description]
sold in collaboration with Solvias AG | [reaction suitability]
reaction type: Asymmetric synthesis
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| Questions And Answer | Back Directory | [Reaction]
- Useful ligand for the Pd-catalyzed amination reaction.
- Ligand used for the Pd-catalyzed arylation of phenols.
- Useful ligand for the Suzuki-Miyaura coupling.
- Ligand used for the Sonagashira reaction of aryl bromides
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Energy Chemical
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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LaaJoo
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