| Identification | More | [Name]
DIETHYLPHOSPHORAMIDOUS DICHLORIDE | [CAS]
1069-08-5 | [Synonyms]
DICHLORO(DIETHYLAMINO)PHOSPHINE
(DIETHYLAMINO)DICHLOROPHOSPHINE
(DIETHYLAMINO)PHOSPHONOUS DICHLORIDE
DIETHYLPHOSPHORAMIDOUS DICHLORIDE
N,N-Diethylphosphoramidous Dichloride | [EINECS(EC#)]
628-166-5 | [Molecular Formula]
C4H10Cl2NP | [MDL Number]
MFCD00013614 | [Molecular Weight]
174.01 | [MOL File]
1069-08-5.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow liquid | [Boiling point ]
179 °C (lit.) | [density ]
1.196 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.497(lit.)
| [Fp ]
181 °F
| [storage temp. ]
0-6°C | [form ]
Liquid | [pka]
-1.49±0.70(Predicted) | [color ]
Clear colorless | [Water Solubility ]
Reacts violently in water. | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/C4H10Cl2NP/c1-3-7(4-2)8(5)6/h3-4H2,1-2H3 | [InChIKey]
BPEMCEULJQTJMI-UHFFFAOYSA-N | [SMILES]
P(N(CC)CC)(Cl)Cl | [CAS DataBase Reference]
1069-08-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29310099 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
DIETHYLPHOSPHORAMIDOUS DICHLORIDE is clear colorless to light yellow liquid
| [Uses]
Reagent for the preparation of diethylaminophosphine-metal complexes and the phosphitylation of alcohols. | [Uses]
Dichloro(diethylamino)phosphine is used as a reagent for the preparation of diethylaminophosphine-metal complexes and it is a critical starting material in the preparation of various phosphines, phosphoramidites & the phosphitylation of alcohols. | [Uses]
DIETHYLPHOSPHORAMIDOUS DICHLORIDE is a useful reagent for the efficient phosphorylation of alcohols.
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|