| Identification | More | [Name]
2-Allyloxyethanol | [CAS]
111-45-5 | [Synonyms]
2-(2-propenyloxy)-ethanol
2-ALLYLOXYETHANOL
ALLYL 2-HYDROXYETHYL ETHER
ALLYL GLYCOL
ALLYL HYDROXYETHYL ETHER
ETHYLENE GLYCOHOL MONOALLYL ETHER
ETHYLENE GLYCOL ALLYL ETHER
ETHYLENE GLYCOL MONOALLYL ETHER
2-(2-propenyloxy)-ethano
2-(allyloxy)-ethano
2-Alloxyethanol
Allyl Cellosolve
allylcellosolve
Ethanol, 2-(allyloxy)-
USAF do-47
usafdo-47
Ethylene glycol monallyl ether
2-Prop-2-enoxyethanol
2-Allyloxyethyl alcohol | [EINECS(EC#)]
203-871-7 | [Molecular Formula]
C5H10O2 | [MDL Number]
MFCD00020607 | [Molecular Weight]
102.13 | [MOL File]
111-45-5.mol |
| Chemical Properties | Back Directory | [Boiling point ]
159 °C(lit.) | [density ]
0.955 g/mL at 25 °C(lit.)
| [vapor pressure ]
1.842hPa at 25℃ | [refractive index ]
n20/D 1.436(lit.)
| [Fp ]
150 °F
| [storage temp. ]
2-8°C | [solubility ]
Completely miscible in water | [form ]
clear liquid | [pka]
14.50±0.10(Predicted) | [color ]
Colorless to Almost colorless | [Specific Gravity]
0.955 | [Odor]
mild mushroom | [Water Solubility ]
454g/L at 25℃ | [InChI]
1S/C5H10O2/c1-2-4-7-5-3-6/h2,6H,1,3-5H2 | [InChIKey]
GCYHRYNSUGLLMA-UHFFFAOYSA-N | [SMILES]
C=CCOCCO | [LogP]
-0.12 at 20℃ | [CAS DataBase Reference]
111-45-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Ethanol, 2-(2-propenyloxy)-(111-45-5) | [EPA Substance Registry System]
111-45-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R38:Irritating to the skin.
R41:Risk of serious damage to eyes.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
NA 1993 / PGIII | [WGK Germany ]
2
| [RTECS ]
KJ5425000
| [TSCA ]
TSCA listed | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29094990 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Dam. 1
Skin Irrit. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless transparent liquid | [Uses]
2-allyloxyethanol could synthesize a new ester (Las9) with lasalocid. Las9 could form complexes with LiC, NaC, KC, RbC, and CsC cations. 2-allyloxyethanol could be used as an end-capping reagent to synthesize 2-allyloxyethanol-terminated polyurethane which is a modifier of polyurethane-modified polydimethylsiloxane (PUMS) coating[1-2].
| [Preparation]
2-allyloxyethanol is produced from Allyl alcohol and Ethylene under pressure and in the presence of a catalyst.
| [Flammability and Explosibility]
Flammable | [Solubility in organics]
Soluble in alcohol and oils.
| [References]
[1] Rados?aw Pankiewicz, Bogumil Brzezinski, Grzegorz Schroeder. “Spectroscopic and PM5 semiempirical study of a new lasalocid ester with 2-allyloxyethanol and its complexes with monovalent cations.” Journal of Molecular Structure 789 1 (2006): Pages 1-7.
[2] Zhe Sun . “Polyurethane covalently modified polydimethylsiloxane (PDMS) coating with increased surface energy and re-coatability.” Progress in Organic Coatings 146 (2020): Article 105744.
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