ChemicalBook--->CAS DataBase List--->1226-46-6

1226-46-6

1226-46-6 Structure

1226-46-6 Structure
IdentificationMore
[Name]

4,4'-Bis(dimethylamino)thiobenzophenone
[CAS]

1226-46-6
[Synonyms]

4,4'-BIS(DIMETHYLAMINO)THIOBENZOPHENONE
4,4-BIS(DIMETHYLAMINO)THIOBENZOPHENONE
Bis-4-(dimethylamino)phenylmethanethione
MICHLER THIOKETONE
N,N,N',N'-TETRAMETHYL-4,4'-DIAMINOTHIOBENZOPHENONE
P,P'-TETRAMETHYLDIAMINOTHIOBENZOPHENONE
THIOMICHLER'S KETONE
Benzophenone, 4,4'-bis(dimethylamino)thio-
bis[4-(dimethylamino)phenyl]-methanethion
Methanethione, bis[4-(dimethylamino)phenyl]-
Michler's thioketone
Michler's thione
p,p'-bis(Dimethylamino)thiobenzophenone
THIOMICHLER,SKETONE(SENSITIVESPEC
4,4'-Bis(dimethylamino)thiobenzophenone (Thiomicheler's ketone)
4,4''-BIS(DIMETHYLAMINO)THIOBENZOPHENONE 96+%
Thiomichler's Ketone [Sensitive spectrophotometric reagent for Au, Ag, Hg and Pd, use for the determination of residual chlorine]
4,4'-Bis(dimethylamino)[carbonothioylbisbenzene]
4,4'-Carbonothioylbis(N,N-dimethylbenzenamine)
Bis[4-(dimethylamino)phenyl] thioketone
[EINECS(EC#)]

214-962-6
[Molecular Formula]

C17H20N2S
[MDL Number]

MFCD00040477
[Molecular Weight]

284.42
[MOL File]

1226-46-6.mol
Chemical PropertiesBack Directory
[Melting point ]

202-206 °C(lit.)
[Boiling point ]

430.0±55.0 °C(Predicted)
[density ]

1.230 g/cm3
[storage temp. ]

Store below +30°C.
[form ]

powder to crystal
[pka]

3.05±0.24(Predicted)
[color ]

Red to Dark red to Dark purple
[InChI]

InChI=1S/C17H20N2S/c1-18(2)15-9-5-13(6-10-15)17(20)14-7-11-16(12-8-14)19(3)4/h5-12H,1-4H3
[InChIKey]

KFUJUTFTRXYQMG-UHFFFAOYSA-N
[SMILES]

C(C1=CC=C(N(C)C)C=C1)(C1=CC=C(N(C)C)C=C1)=S
[CAS DataBase Reference]

1226-46-6(CAS DataBase Reference)
[NIST Chemistry Reference]

4,4'-Bis(dimethylamino)thio benzophenone(1226-46-6)
[EPA Substance Registry System]

1226-46-6(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

2811
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HS Code ]

29309070
[Storage Class]

11 - Combustible Solids
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N,N,N',N'-Tetramethyl-4,4'-diaminothiobenzophenone(1226-46-6).msds
Hazard InformationBack Directory
[Chemical Properties]

Purple crystal
[Uses]

Thiomichler's ketone (4,4'-Bis(dimethylamino)thiobenzophenone) can be used as a photometric reagent for the determination of gold, palladium, platinum, mercury, silver, and copper. Thiomichler's ketone is a kind of biological materials or organic compounds that are widely used in life science research[1].
[Purification Methods]

Purify the thioketone by recrystallisation from hot EtOH or by trituration with a small volume of CHCl3, followed by filtration and washing with hot EtOH [Terbell & Wystrade J Phys Chem 68 2110 1964]. Also it recrystallises from CHCl3/ MeOH. [Beilstein 14 H 101, 14 I 395, 14 II 60.]
[References]

[1] Bergmeyer H U, et al. Biochemical reagents[M]//Methods of Enzymatic Analysis. Academic Press, 1965: 967-1037.
Spectrum DetailBack Directory
[Spectrum Detail]

4,4'-Bis(dimethylamino)thiobenzophenone(1226-46-6)MS
4,4'-Bis(dimethylamino)thiobenzophenone(1226-46-6)1HNMR
4,4'-Bis(dimethylamino)thiobenzophenone(1226-46-6)13CNMR
4,4'-Bis(dimethylamino)thiobenzophenone(1226-46-6)IR1
4,4'-Bis(dimethylamino)thiobenzophenone(1226-46-6)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

1226-46-6(sigmaaldrich)
[TCI AMERICA]

Thiomichler's Ketone  [Sensitive spectrophotometric reagent for Au, Ag, Hg and Pd, use for the determination of residual chlorine](1226-46-6)
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