| Identification | Back Directory | [Name]
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE | [CAS]
127593-28-6 | [Synonyms]
-binaphthyl]palladium(II)
Dichloro[(S)-(−
Dichloro[(S)-()-2,2′-bis(dip
-bis(diphenylphosphino)-1,1′
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYLPALLADIUM(II) CHLORIDE
[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)
((S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium
Dichloro[(S)-()-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladiuM(II)
[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE
Dichloro[(S)-(-)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]palladiuM(II)
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),Min.98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
REF DUPL: [(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium (II) chloride
Palladium,[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-kP]]dichloro-, (SP-4-2)-
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),98% (S-BINAP)PdCl2
PALLADIUM, [(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[DIPHENYLPHOSPHINE-.KAPPA.P]]DICHLORO-, (SP-4-2)- | [EINECS(EC#)]
1312995-182-4 | [Molecular Formula]
C44H32Cl2P2Pd | [MDL Number]
MFCD00075254 | [MOL File]
127593-28-6.mol | [Molecular Weight]
800 |
| Chemical Properties | Back Directory | [Melting point ]
>300°C | [storage temp. ]
Inert atmosphere,2-8°C | [InChIKey]
VDHAUMFISVWIRX-UHFFFAOYSA-L | [SMILES]
[Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC3=CC=CC=C3C=2C2C3=CC=CC=C3C=CC=2P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-] | [CAS DataBase Reference]
127593-28-6 |
| Questions And Answer | Back Directory | [Uses]
[(S)-(-)-2,2-bis(diphenylphosphine)-1,1-binaphthyl]palladium dichloride is an organometallic derivative that can be used as a noble metal catalyst. | [Reaction]
- Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.
- Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction.
- Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.
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