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132071-87-5

132071-87-5 Structure

132071-87-5 Structure
IdentificationBack Directory
[Name]

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
[CAS]

132071-87-5
[Synonyms]

Dichlorobisdiphenylphosphinobinaphthylruthenium
(R)-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]dichlororutheniuM
(R)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 95%
Dichloro〔(R)-(+)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(Ⅱ)
[(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
[(R)-(+)-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl] ruthenium dichloride
DICHLORO[(S)-(-)-,2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Dichloro [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphathyl] rutheniuM(II)
[(R)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),min.95%
DICHLORO[(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER
DICHLORO[(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1, 1'-binaphthyl]ruthenium(II), min. 95%
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),(R-BINAP)RuCl2
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(R)-BINAP]RuCl2
[EINECS(EC#)]

623-973-9
[Molecular Formula]

C44H32Cl2P2Ru
[MDL Number]

MFCD01073794
[MOL File]

132071-87-5.mol
[Molecular Weight]

794.65
Chemical PropertiesBack Directory
[Melting point ]

>300 ºC
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[color ]

orange
[Sensitive ]

air sensitive
[InChIKey]

YEKBVMDAGDTOQB-UHFFFAOYSA-L
[SMILES]

C1(C2C3C=CC=CC=3C=CC=2P(C2=CC=CC=C2)C2=CC=CC=C2)C2C=CC=CC=2C=CC=1P(C1=CC=CC=C1)C1C=CC=CC=1.[Ru](Cl)Cl
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39-36/37
[WGK Germany ]

WGK 3
[HS Code ]

2931.90.6000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Reaction]

  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
Reactions of 132071-87-5
Hazard InformationBack Directory
[Uses]

(R)?-?[2,?2''-?Bis(diphenylphosphin?o)?-?1,?1''-?binaphthyl]?dichlororuthenium is a catalyst used in the synthesis of helicobacter pylori lipopolysaccharide structures displaying anti-inflammatory activiy.
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