ChemicalBook--->CAS DataBase List--->13209-15-9

13209-15-9

13209-15-9 Structure

13209-15-9 Structure
IdentificationMore
[Name]

ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE
[CAS]

13209-15-9
[Synonyms]

1,2-BIS(DIBROMOMETHYL)BENZENE
A,A,A',A'-TETRABROMO-O-XYLENE
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-2-XYLENE
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE
ALPHA,ALPHA,BETA,BETA-TETRABROMO-O-XYLENE
O-XYLYLENE TETRABROMIDE
1,2-bis(dibromomethyl)-benzen
Benzene,1,2-bis(dibromomethyl)-
2-(m-Aminobenzenesulfamido)-6,8-Disulfonic Acid
ALPHA ALPHA ALPHA' ALPHA'-TETRABROMO-O-&
a,a,a,a-Tertabromo-O-Xylene
à,à,à',à'-tetrabromo-o-xylene
AAAATETRABROMOORTHOXYLENE
ɑ,ɑ,ɑ',ɑ'-Tetrabromo-o-xylene, 97%
1,2-Phenylenebis(dibromomethane)
[EINECS(EC#)]

236-176-2
[Molecular Formula]

C8H6Br4
[MDL Number]

MFCD00000131
[Molecular Weight]

421.75
[MOL File]

13209-15-9.mol
Chemical PropertiesBack Directory
[Appearance]

OFF-WHITE TO GREY CRYSTALLINE POWDER
[Melting point ]

114-116 °C(lit.)
[Boiling point ]

303.01°C (rough estimate)
[density ]

2.2654 (rough estimate)
[refractive index ]

1.7040 (estimate)
[storage temp. ]

Store below +30°C.
[form ]

Liquid or Low Melting Solid
[color ]

Clear colorless to yellow
[Water Solubility ]

Insoluble
[BRN ]

2211698
[InChI]

InChI=1S/C8H6Br4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4,7-8H
[InChIKey]

LNAOKZKISWEZNY-UHFFFAOYSA-N
[SMILES]

C1(C(Br)Br)=CC=CC=C1C(Br)Br
[CAS DataBase Reference]

13209-15-9(CAS DataBase Reference)
[EPA Substance Registry System]

13209-15-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)Environment (GHS09)
GHS05,GHS07,GHS09
[Signal word ]

Danger
[Hazard statements ]

H314-H335-H400
[Precautionary statements ]

P260-P271-P273-P280-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R36/37:Irritating to eyes and respiratory system .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

19-21
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29039990
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Aquatic Acute 1
Eye Dam. 1
Skin Corr. 1B
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

OFF-WHITE TO GREY CRYSTALLINE POWDER
[Uses]

α,α,α′,α′-Tetrabromo-o-xylene can be employed as a precursor for the synthesis of:
  • Poly(o-phenylene vinylene) (o-PPV) via electrochemical polymerization.
  • A pentacene derivative by reacting with naphthalene moieties for the development of organic thin-film transistors (OTFTs).
  • Bitopic pyrazole containing ligands.

[Uses]

α,α,α',α'-Tetrabromo-o-xylene reacts with 5endo,6endo-bis-chlormethyl-norborn-2-en to obtain trans/cis-2,3-bis(chloromethyl)-1,4-methano-1,2,3,4-tetrahydroanthracene. Further, it is involved in the preparation of 1-(3-butenyl)-2-(deuteriomethyl)benzene by reacting with allylmagnesium bromide. In addition this, it is used to prepare exo-benzocyclobuteno-1,2,3,4-tetrahydro-1,4-methanoanthracene by reacting with exo-1,4,4a,8b-tetrahydro-1,4-methanobiphenylene.
Spectrum DetailBack Directory
[Spectrum Detail]

ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)MS
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)1HNMR
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)13CNMR
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)IR1
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)IR2
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)IR3
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

alpha,alpha,alpha',alpha'-Tetrabromo-o-xylene, 97%(13209-15-9)
[Alfa Aesar]

alpha,alpha,alpha',alpha'-Tetrabromo-o-xylene, 97%(13209-15-9)
[Sigma Aldrich]

13209-15-9(sigmaaldrich)
[TCI AMERICA]

alpha,alpha,alpha',alpha'-Tetrabromo-o-xylene,>96.0%(GC)(13209-15-9)
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