| Identification | More | [Name]
Butyltriphenylphosphonium chloride | [CAS]
13371-17-0 | [Synonyms]
BTC
BUTYLTRIPHENYLPHOSPHONIUM CHLORIDE
TRIPHENYLBUTYLPHOSPHONIUM CHLORIDE
butyltriphenyl-phosphoniuchloride
BUTYLTRIPHENYL PHOSPHONIUM CHLORIDE 98%
Phosphonium, butyltriphenyl-, chloride
(1-Butyl)triphenylphosphonium chloride | [EINECS(EC#)]
236-443-3 | [Molecular Formula]
C22H24ClP | [MDL Number]
MFCD00040546 | [Molecular Weight]
354.85 | [MOL File]
13371-17-0.mol |
| Chemical Properties | Back Directory | [Appearance]
white to off-white crystalline powder | [Melting point ]
226-230 °C(lit.) | [Fp ]
>270°C | [storage temp. ]
Store below +30°C. | [solubility ]
soluble in Methanol | [form ]
solid | [color ]
White to Light yellow | [Optical Rotation]
233.2-237.8℃° | [Water Solubility ]
soluble | [Sensitive ]
Hygroscopic | [InChI]
1S/C22H24P.ClH/c1-2-3-19-23(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,2-3,19H2,1H3;1H/q+1;/p-1 | [InChIKey]
MFIUDWFSVDFDDY-UHFFFAOYSA-M | [SMILES]
[P+](CCCC)(c3ccccc3)(c2ccccc2)c1ccccc1.[Cl-] | [CAS DataBase Reference]
13371-17-0(CAS DataBase Reference) | [EPA Substance Registry System]
13371-17-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
6.1 | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral | [Toxicity]
LD50 orally in Rabbit: 320 mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
white to off-white crystalline powder | [Synthesis]
7.86 g (0.03 mol) triphenylphosphine was added with 20 ml acetonitrile to a fitted with a condenser tube.
100 ml three-necked flask, nitrogen protection under constant pressure dropwise addition of 8 mL (0.06 mol) bromobutane, reflux stirring reaction 10 |
| Questions And Answer | Back Directory | [Application]
Butyltriphenylphosphine chloride is a quaternary phosphonium salt containing a monoalkyltriphenyl substituent. The phosphorus atom possesses three unpaired electrons, one lone pair of electrons, and five empty 3d orbitals, giving Ph3P+ electron-withdrawing properties. This also allows the quaternary phosphonium salt cation to bind well with F-, which is beneficial for fluorination reactions. Due to its good catalytic effect, high selectivity, high thermal stability, low toxicity, and recyclability, quaternary phosphonium salt phase transfer catalysts have been widely used in recent years. |
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