| Identification | More | [Name]
N-Fluorobenzenesulfonimide | [CAS]
133745-75-2 | [Synonyms]
N-FLUOROBENZENESULFONAMIDE
N-FLUOROBENZENESULFONIMIDE
N-FLUOROBENZENESULPHONIMIDE
N-FLUOROBIS(PHENYLSULFONYL)AMINE
N-FLUORODIBENZENESULFONAMIDE
N-FLUORODIBENZENESULFONIMIDE
N-FLUORODI(BENZENESULFONYL)AMINE
NFSI
N-Fluoro Dibenzenesulfonic amide
Benzenesulfonamide, N-fluoro-N-(phenylsulfonyl)-
accufluor nfsi
N-Fluorodibenzenesulfonimide (NFSI)
N-Fluorobenzenesulfonimide [Fluorinating Reagent]
N-Fluorodi(benzenesulfonyl)amine, N-Fluorodibenzenesulfonimide, NFSI
N-Fluorobenzenesulfonimide, N-Fluorodibenzenesulfonimide, NFSI
bis(phenylsulfonyl)fluoroamine (N-FLUOROBENZENESULFONIMIDE)
Bis(phenylsulfonyl)fluoroamine | [EINECS(EC#)]
-0 | [Molecular Formula]
C12H10FNO4S2 | [MDL Number]
MFCD00144885 | [Molecular Weight]
315.34 | [MOL File]
133745-75-2.mol |
| Chemical Properties | Back Directory | [Appearance]
Off-white to light brown crystalline powder | [Melting point ]
114-116 °C
| [Boiling point ]
471.4±28.0 °C(Predicted) | [density ]
1.4466 (estimate) | [Fp ]
110℃ | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Very soluble in acetonitrile, dichloromethane or THF and less soluble in toluene. | [form ]
solid | [pka]
-32.45±0.70(Predicted) | [color ]
white | [BRN ]
5348902 | [InChIKey]
RLKHFSNWQCZBDC-UHFFFAOYSA-N | [CAS DataBase Reference]
133745-75-2(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,O | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
10 | [Hazard Note ]
Oxidising Agent | [TSCA ]
No | [HazardClass ]
IRRITANT | [HS Code ]
29350090 |
| Hazard Information | Back Directory | [Chemical Properties]
Off-white to light brown crystalline powder | [Uses]
Versatile fluorinating reagent used in the fluorination of aryls, enolates, carbanions, organolithiums, etc. | [Application]
N-Fluorobenzenesulfonimide is a mild electrophilic fluorinating reagent, that can also be used as a strong oxidant for the promotion of reductive elimination from transition metals.
| [General Description]
N-Fluorobenzenesulfonimide (NFSi) is a commonly used electrophilic fluorinating agent in organic synthesis to introduce fluorine into neutral organic molecules. It is also used to fluorinate nucleophilic substrates such as reactive organometallic species and malonate anions.
NFSi can be synthesized by the reaction of benzenesulfonimide with fluorine. |
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