| Identification | More | [Name]
Fenpyroximate | [CAS]
134098-61-6 | [Synonyms]
1,1-dimethylethyl (e)-4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy)methyl)benzoate
4-[[[[(1,3-Dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]-benzoic acid 1,1-dimethylethyl ester
DANITORON
DANITRON
FENPYROXIMATE
KIRON
ORTUS
PAMANRIN
tert-butyl (e)-4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy)methyl)benzoate
1,1-dimethylethylester,(e)-)methyl)
4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy)methyl)-,1,1-dimethylethylester,benzoicaci
benzoicacid,4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy
nni850
t-butyl(e)-alpha-(1,3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy)-p-tol
uate
Danitron,Ortus
E-1,1-dimethylethyl 4-(((1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl) methylene) amino) oxy methyl benzoate
fenproximate
tert-butyl(E)-α-(1,3-dimethyl-5-phenoxy-pyrazol-4-ylmethyleneaminoxy)-ptoluate
Fenbpyroximate | [Molecular Formula]
C24H27N3O4 | [MDL Number]
MFCD00274596 | [Molecular Weight]
421.49 | [MOL File]
134098-61-6.mol |
| Chemical Properties | Back Directory | [Melting point ]
101.1-102.4° | [Boiling point ]
546.2±60.0 °C(Predicted) | [density ]
1.25g/cm3 | [storage temp. ]
Store at -20°C | [solubility ]
Chloroform: Slightly soluble,Methanol: Slightly soluble | [Water Solubility ]
Insoluble in water | [form ]
powder to crystal | [pka]
1.58±0.10(Predicted) | [color ]
White to Light yellow to Light orange | [Stability:]
Light Sensitive | [Major Application]
agriculture
environmental | [InChI]
1S/C24H27N3O4/c1-17-21(22(27(5)26-17)30-20-9-7-6-8-10-20)15-25-29-16-18-11-13-19(14-12-18)23(28)31-24(2,3)4/h6-15H,16H2,1-5H3/b25-15+ | [InChIKey]
YYJNOYZRYGDPNH-MFKUBSTISA-N | [SMILES]
Cc1nn(C)c(Oc2ccccc2)c1\C=N\OCc3ccc(cc3)C(=O)OC(C)(C)C | [LogP]
6.443 (est) | [CAS DataBase Reference]
134098-61-6(CAS DataBase Reference) | [EPA Substance Registry System]
134098-61-6(EPA Substance) |
| Safety Data | Back Directory | [RIDADR ]
UN3082 (liquid) | [WGK Germany ]
WGK 3 | [HS Code ]
29331990 | [Storage Class]
6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | [Hazard Classifications]
Acute Tox. 2 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1B | [Hazardous Substances Data]
134098-61-6(Hazardous Substances Data) | [Toxicity]
LD50 in male, female rats (mg/kg): 480, 245 orally; >2000, >2000 dermally; LC50 (48hr) in carp: 6.1 mg/l; LC50 (3hr) in daphnia pulex: 85 mg/l (Konno) |
| Hazard Information | Back Directory | [Uses]
Acaricide. | [Definition]
ChEBI: Fenpyroximate is a pyrazole acaricide and a tert-butyl ester. It has a role as a mitochondrial NADH:ubiquinone reductase inhibitor. It derives from a hydride of a 1H-pyrazole. | [Agricultural Uses]
Acaricide, Miticide, Insecticide: Used to control spider mites in greenhouses. | [Trade name]
AKARI®; HOE® 555-02A; NNI®-850;
SEQUEL® | [Metabolic pathway]
When fenpyroximate is administered orally to rats,
radiocarbons from 14C-fenpyroximate are rapidly and
almost completely excreted in the urine and feces
within 72 h, and fenyproximate seems to be
metabolized via oxidation of the tert-butyl group and
methyl group at the 3-position in the pyrazole ring, p-
hydroxylation in the phenoxy moiety, N-demethylation,
hydrolysis of the tert-butyl ester, cleavage of the oxime ether bond, and/or E/Z isomerization. In soils, 12
degradation products are identified, and in sterilized
soils the degradation of fenpyroximate and CO2,
evolution are negligible. Fenpyroximate degrades
through hydrolysis of tert-butyl ester, isomerization or
cleavage of the oxime ether, N-demethylation,
oxidation of the methyl group at the 3-position on the
pyrazole ring, and hydroxylation of the phenoxy ring,
and is finally mineralized to CO2 and/or bound to soil
organic matter. |
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