| | Identification | More |  | [Name] 
 Managanese bromide
 |  | [CAS] 
 13446-03-2
 |  | [Synonyms] 
 MANGANESE BROMIDE
 MANGANESE BROMIDE (OUS)
 MANGANESE (II) BROMIDE
 Manganese bromide (MnBr2)
 manganesebromide(mnbr2)
 Manganous bromide
 Manganousbromide
 MnBr2
 Manganese(II) bromide anhydrous
 MANGANESE (II) BROMIDE ANHYDROUS 95%
 MANGANESE (II) BROMIDE, ANHYDROUS, 99%, H2O <0.1%
 Manganese(II)bromide,anhydrous,95%
 Managanese bromide
 Manganese dibromide
 Manganese(II) bromide, anhydrous, 99%, H2O <0.3%
 Manganese (II) bromide, 99.9% (metals basis)
 Dibromomanganese
 Manganese(ii) bromide, 99%, anhydrous
 Dibromomanganese(II)
 Manganese(II) dibromide
 |  | [EINECS(EC#)] 
 236-591-9
 |  | [Molecular Formula] 
 Br2Mn
 |  | [MDL Number] 
 MFCD00011113
 |  | [Molecular Weight] 
 214.75
 |  | [MOL File] 
 13446-03-2.mol
 | 
 | Chemical Properties | Back Directory |  | [Appearance] 
 Reddish  crystalline  powder
 |  | [Melting point ] 
 698°C
 |  | [density ] 
 4.385 g/mL at 25 °C(lit.)
 
 |  | [form ] 
 Powder
 |  | [color ] 
 Pink
 |  | [Specific Gravity] 
 4.38
 |  | [Stability:] 
 Stable, but very hygroscopic. Incompatible with strong oxidizing agents. Store under a dry atmosphere.
 |  | [Water Solubility ] 
 Soluble in water. (1273g/L)
 |  | [Sensitive ] 
 Hygroscopic
 |  | [Merck ] 
 14,5725
 |  | [Exposure limits] 
 ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3
 OSHA: Ceiling 5 mg/m3
 NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
 |  | [InChI] 
 InChI=1S/2BrH.Mn/h2*1H;/q;;+2/p-2
 |  | [InChIKey] 
 RJYMRRJVDRJMJW-UHFFFAOYSA-L
 |  | [SMILES] 
 [Mn](Br)Br
 |  | [CAS DataBase Reference] 
 13446-03-2(CAS DataBase Reference)
 |  | [NIST Chemistry Reference] 
 Manganese bromide(13446-03-2)
 |  | [EPA Substance Registry System] 
 13446-03-2(EPA Substance)
 | 
 | Safety Data | Back Directory |  | [Hazard Codes ] 
 Xn
 |  | [Risk Statements ] 
 R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
 |  | [Safety Statements ] 
 S36:Wear suitable protective clothing .
 |  | [WGK Germany ] 
 3
 
 |  | [F ] 
 3-10
 |  | [TSCA ] 
 Yes
 |  | [HS Code ] 
 28275900
 | 
 | Hazard Information | Back Directory |  | [Hazard] 
 Irritant.
 |  | [Chemical Properties] 
 Reddish  crystalline  powder
 |  | [Uses] 
 It can be used in place of?palladium?in the?Stille reaction, which couples two carbon atoms using an?organotin compound.
 |  | [Purification Methods] 
 It forms rose-red deliquescent crystals which are soluble in EtOH. The H2O is removed by heating at 100o then in HBr gas at 725o, or dry it in an atmosphere of N2 at 200o.
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