| Identification | More | [Name]
LITHIUM METABORATE | [CAS]
13453-69-5 | [Synonyms]
LITHIUM BORATE (META)
LITHIUM METABORATE
LITHIUM METABORATE 2-HYDRATE
SPECTROMELT A 20
SPECTROMELT C 20
SPECTROMELT(R) C20
boricacid(hbo2),lithiumsalt
Boricacidlithiumsalt
lithiummetaborate,anhydrous
Lithiummetaborate,octahydrat
Lithium metaborate, 99.995% metals basis
LITHIUM METABORATE ACS REAGENT
LITHIUM METABORATE, 98+%, A.C.S. REAGENT
Lithium metaborate, 99.9+% metals basis
LithiumMetaborateAnhydrousGr
Lithium metaborate, 99+%
Lithium metaborate, pure, 99%
LITHIUM METABORATE, ANHYDROUS BIO-REFINED
LITHIUM METABORATE, ANHYDROUS REAGENT
LITHIUM METABORATE, ANHYDROUS REAGENT (ACS) | [EINECS(EC#)]
236-631-5 | [Molecular Formula]
BLiO2 | [MDL Number]
MFCD00011089 | [Molecular Weight]
49.75 | [MOL File]
13453-69-5.mol |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
845 °C (lit.) | [bulk density]
1300kg/m3 | [density ]
1,4 g/cm3 | [storage temp. ]
Store at +5°C to +30°C. | [solubility ]
soluble in ethanol. | [form ]
Powder | [color ]
White | [Specific Gravity]
1.4 | [Stability:]
Stable. | [Water Solubility ]
Soluble in water(27.5g/L). | [Specific Heat Capacity]
Cp(crystal):1.15533J/(g·K),at 25℃ | [Sensitive ]
Hygroscopic | [Exposure limits]
ACGIH: TWA 2 mg/m3; STEL 6 mg/m3 | [Major Application]
battery precursors
catalysts
material synthesis precursor | [InChI]
InChI=1S/BHO2.Li.H/c2-1-3;;/h2H;; | [InChIKey]
YMSYNVBIEXZZJS-UHFFFAOYSA-N | [SMILES]
B(=O)O.[LiH] | [CAS DataBase Reference]
13453-69-5(CAS DataBase Reference) | [EPA Substance Registry System]
Lithium metaborate (13453-69-5) |
| Safety Data | Back Directory | [Symbol(GHS) ]
  
GHS05,GHS07,GHS08 | [Signal word ]
Danger | [Hazard statements ]
H302-H318-H361fd | [Precautionary statements ]
P202-P264-P280-P301+P312-P305+P351+P338-P308+P313 | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R41:Risk of serious damage to eyes. | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
1
| [F ]
3 | [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
28402090 | [Storage Class]
13 - Non Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Dam. 1
Repr. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
Lithium Metaborate is commonly used as a fused compound or a component for an assay. It has been used for the analysis of wild rice for silicon, calcium, magnesium and potassium. Lithium metaborate was used to fuse with solid samples for decomposition. | [Uses]
Lithium metaborate is used for flux.
| [Preparation]
Lithium metaborate, LiBO2, may be prepared by fusing together either lithium hydroxide or lithium carbonate and boric acid in the proper stoichiometric ratio. Recrystallization from water at about room temperature yields lithium metaborate- octahydrate, LiBO2·8H2O. The octahydrate may be dried to yield a dihydrate, LiBO2-2H2O, or a half-hydrate, LiBO2·0.5H2O.
| [General Description]
Lithium metaborate (LiBO2) is the lithium salt of boric acid. It can be synthesized by reacting orthoboric acid with lithium carbonate. Its crystals belong to the monoclinic crystal system having space group P21/c. Three polymorphic forms have been identified on ambient pressure devitrification of LiBO2: α-, γ- and β′-LiBO2. | [Flammability and Explosibility]
Notclassified | [Structure and conformation]
z | [References]
[1] E.I.Kamitsos, A.P.Patsis, M.A.Karakassides, G.D.Chryssikos, Infrared reflectance spectra of lithium borate glasses, Journal of Non-Crystalline Solids, 1990, 126, 52-67.
[2] Li Lei, Duanwei He, Kai He, Jiaqian Qin, Shanmin Wang, Pressure-induced coordination changes in LiBO2, Journal of Solid State Chemistry, 2009, 182, 3041-3048.
[3] Colin D. McMillen, Henry G. Giesber, Joseph W. Kolis, The hydrothermal synthesis, growth, and optical properties of γ-LiBO2, Journal of Crystal Growth, 310, 2008, 299-305. |
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