| Identification | Back Directory | [Name]
COPPER(I)HYDRIDE | [CAS]
13517-00-5 | [Synonyms]
(BDP)Cu(H)
Copper hydride
Hydridecopper(I)
COPPER(I)HYDRIDE
copper monohydride
Cuprous hydride - in toluene
Copper hydride (CuH) solution
Copper hydride (CuH) solution in toluene | [MDL Number]
MFCD16621396 | [MOL File]
13517-00-5.mol |
| Chemical Properties | Back Directory | [Melting point ]
decomposes at >60℃ [KIR78] | [density ]
6.38 [CRC10] | [Fp ]
6℃ | [storage temp. ]
?20°C | [form ]
red-brown solid | [color ]
red-brown | [Water Solubility ]
decomposes in H2O at 65°C [CRC10] | [CAS DataBase Reference]
13517-00-5 |
| Hazard Information | Back Directory | [Chemical Properties]
light reddish brown; composition can vary from Cu0.6 to CuH; can be prepared by precipitation with hypophosphorous acid at 65°C; used as a reducing agent in some organic reactions [KIR78] | [Uses]
Reagent for stereoselective synthesis of exocyclic tetra substituted enol ethers and olefins | [reaction suitability]
core: copper
reagent type: catalyst | [Synthesis]
4CuSO4 + 3H3PO2 + 6H2O==40°C to 50°C== 4CuH↓ + 3H3PO4 + 4H2SO4 ;
This reaction should be carried out in a constant temperature water bath with co |
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