| Identification | Back Directory | [Name]
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE | [CAS]
135620-04-1 | [Synonyms]
(S,S)-Jacbosen
(S,S)-Jacobsencat.
JACOBSEN'S CATALYST
(S,S)-JACOBSEN CATALYST
(S,S)-JACOBSEN'S CATALYST
-1,2-cyclohexanediamine]manganese(III)
(S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX
(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL
(S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL
(S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco
(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo
(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
(1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕manganese(Ⅲ) Chloride
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE
(S,S)-(+)-N,N′-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride
(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride
(1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat.
(1S,2S)-(+)-[1,2-Cyclohexanediammino-N,N'-bis(3,5-di-t-butylsalicylidene)] manganese (III)chloride,98% (S,S)-Jacobsen Cat | [Molecular Formula]
C36H52ClMnN2O2 | [MDL Number]
MFCD02101663 | [MOL File]
135620-04-1.mol | [Molecular Weight]
635.2 |
| Chemical Properties | Back Directory | [Appearance]
dark brown powder | [Melting point ]
330-332 °C(lit.)
| [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
brown | [InChIKey]
VGAJDQCIDNCJQC-JINVCYSXSA-K | [CAS DataBase Reference]
135620-04-1 |
| Hazard Information | Back Directory | [Chemical Properties]
dark brown powder | [Uses]
Reactant involved in:
- Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activity
- Immobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate)
- Synthesis of derivatvies for studies of conformational models of enantioselective reactions
Catalyst involved in:
- Asymmetric epoxidation of olefins
- Immobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols?
- Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene
', 'Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsenμs catalyst has also been used in the asymmetric α-hydroxylation of silyl enol ethers. Catalyst for the enantioselective epoxidation of a variety of olefins. |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
- Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
- Asymmetric Kinetic resolution of secondary alcohols in water.
- Enantioselective Reformatsky reaction with ketones.
|
|
|