| Identification | More | [Name]
(1S,2S)-(+)-1,2-Diaminocyclohexane | [CAS]
21436-03-3 | [Synonyms]
(1S,2S)-(+)-1,2-CYCLOHEXANEDIAMINE
(1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE
(1S,2S)-1,2-DIAMINOCYCLOHEXANE
(1S,2S)-CYCLOHEXANE-1,2-DIAMINE
(1S)-TRANS-1,2-CYCLOHEXANEDIAMINE
(1S)-(+)-TRANS-1,2-DIAMINOCYCLOHEXANE
(1S)-TRANS-1,2-DIAMINOCYCLOHEXANE
S-DACH
(+)-(S,S)-1,2-DIAMINOCYCLOHEXANE
(S,S)-(+)-1,2-DIAMINOCYCLOHEXANE
(S,S)-1,2-DIAMINOCYCLOHEXANE
SS-DAC
(+)-(S,S)-DACH
(S,S)-DACH
SS-DIAMINOCYCLOHEXANE
(1S,2S)-Cyclohexane-1,2-Diamin
(1S,2S)-(+)-1,2-Diaminocyclohexane,99%(S,S)-DACH
(1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE (S,S)-DACH
(1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE 98%
(1S)-trans-1,2-Cyclohexanediamine, (1S)-trans-1,2-Diaminocyclohexane | [Molecular Formula]
C6H14N2 | [MDL Number]
MFCD00062986 | [Molecular Weight]
114.19 | [MOL File]
21436-03-3.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powder | [Melting point ]
40-43 °C (lit.) | [alpha ]
25.25 º (589nm, c=5, 1 M HCl) | [Boiling point ]
104-110 °C/40 mmHg (lit.) | [density ]
0.951 | [refractive index ]
1.4886 | [Fp ]
169 °F
| [storage temp. ]
2-8°C
| [form ]
Crystals or Powder | [pka]
10.76±0.70(Predicted) | [color ]
White to light beige | [Optical Rotation]
[α]20/D +25°, c = 5 in 1 M HCl | [Water Solubility ]
soluble | [Sensitive ]
Air Sensitive | [Detection Methods]
HPLC | [BRN ]
2801645 | [InChI]
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m0/s1 | [InChIKey]
SSJXIUAHEKJCMH-WDSKDSINSA-N | [SMILES]
N[C@H]1CCCC[C@@H]1N | [CAS DataBase Reference]
21436-03-3(CAS DataBase Reference) | [NIST Chemistry Reference]
(1S,2S)-(+)-1,2-Diaminocyclohexane(21436-03-3) | [Storage Precautions]
Store under nitrogen |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3259 8/PG 3
| [WGK Germany ]
3
| [F ]
10-34 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29213000 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powder | [Uses]
suzuki reaction | [Purification Methods]
Distil or recrystallise the diamine from pet ether under N2 or Ar. Store it as above. The 1S,2S-base D-tartrate salt has M 264.3, m 180 -1 8 4o(dec) and [] 25 -12.5o (c 4, H2O) from which the free base can be purified or optically enriched. It is a useful chiral synthon. [Fjii et al. J Chem Soc, Chem Commun 45 1985, Takahashi et al. Tetrahedron Lett 30 7095 1989, Hanassian et al. J Org Chem 58 1991 1993, Beilstein 13 III 7.] |
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