| Identification | Back Directory | [Name]
DIMETHYLSILYLDIETHYLAMINE | [CAS]
13686-66-3 | [Synonyms]
DK066
DIMETHYLSILYLDIETHYLAMINE
DIETHYLAMINODIMETHYLSILANE
N,N-Diethyldimethylsilanamine
N-dimethylsilyl-N-ethylethanamine
N,N-DIETHYL-1,1-DIMETHYLSILYLAMINE
n,n-diethyl-1,1-dimethyl-silanamin
N,N-diethyl-1,1-dimethyl-Silanamine
Silanamine,N,N-diethyl-1,1-dimethyl-
DIMETHYLSILYLDIETHYLAMINE ISO 9001：2015 REACH | [EINECS(EC#)]
237-202-5 | [Molecular Formula]
C6H17NSi | [MDL Number]
MFCD00048523 | [MOL File]
13686-66-3.mol | [Molecular Weight]
131.29 |
| Hazard Information | Back Directory | [Physical properties]
bp 112°C/760 mmHg; n20
D 1.4087; d20
4 0.7505
g cm?3. | [Uses]
N,N-Diethylaminodimethylsilane is a
useful reagent for the conversion of hydroxy groups of allyl
or homoallyl alcohols into hydrodimethylsilyl ethers for use in
intramolecular hydrosilation reactions. In some cases, N,N-diethylaminodimethylsilane
gives superior results compared to the
more commonly employed 1,1,3,3-tetramethyldisilazane (eq 1). | [Preparation]
by treatment of commercially available
chlorodimethylsilane (ClMe2SiH) and diethylamine in the
presence of triethylamine in ether, followed by filtration and
distillation. |
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