ChemicalBook--->CAS DataBase List--->14468-90-7

14468-90-7

14468-90-7 Structure

14468-90-7 Structure
IdentificationMore
[Name]

1-TRIMETHYLSILYL-2-PYRROLIDINONE
[CAS]

14468-90-7
[Synonyms]

1-TRIMETHYLSILYL-2-PYRROLIDINONE
1-TRIMETHYLSILYLPYRROLIDONE
N-TRIMETHYLSILYL-2-PYRROLIDINONE
N-TRIMETHYLSILYL-2-PYRROLIDONE
N-Trimethylsilylbutyrolactam~N-Trimethylsilyl-2-pyrrolidone
1-(trimethylsilyl)pyrrolidin-2-one
n-trimethylsilylbutyrolactam
1-(Trimethylsilanyl)pyrrolidin-2-one
1-Trimethylsilyl-2-pyrrolizinone
[EINECS(EC#)]

238-461-7
[Molecular Formula]

C7H15NOSi
[MDL Number]

MFCD00051572
[Molecular Weight]

157.29
[MOL File]

14468-90-7.mol
Chemical PropertiesBack Directory
[Appearance]

Colourless Liquid
[Boiling point ]

90 °C/20 mmHg (lit.)
[density ]

0.821
[refractive index ]

1.4590
[Fp ]

53°C
[storage temp. ]

Storage temp. 2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Oil
[pka]

-0.11±0.20(Predicted)
[color ]

Clear Colourless
[Specific Gravity]

0.821
[Water Solubility ]

It hydrolyzes with water.
[Sensitive ]

Moisture Sensitive
[BRN ]

114950
[Stability:]

Store desiccated in freezer
[InChI]

1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
[InChIKey]

LUBVCBITQHEVCJ-UHFFFAOYSA-N
[SMILES]

C[Si](C)(C)N1CCCC1=O
[CAS DataBase Reference]

14468-90-7(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Warning
[Hazard statements ]

H226-H315-H319-H335
[Precautionary statements ]

P280g-P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R10:Flammable.
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

1993
[WGK Germany ]

3
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

2933790090
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

Colourless Liquid
[Uses]

1-Trimethylsilyl-2-pyrrolidinone, is used as a fine chemical intermediate.
[General Description]

1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.
Spectrum DetailBack Directory
[Spectrum Detail]

1-TRIMETHYLSILYL-2-PYRROLIDINONE(14468-90-7)MS
1-TRIMETHYLSILYL-2-PYRROLIDINONE(14468-90-7)1HNMR
1-TRIMETHYLSILYL-2-PYRROLIDINONE(14468-90-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1-Trimethylsilyl-2-pyrrolidinone, 96%(14468-90-7)
[Sigma Aldrich]

14468-90-7(sigmaaldrich)
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