| Identification | More | [Name]
SAMARIUM NITRATE HEXAHYDRATE | [CAS]
13759-83-6 | [Synonyms]
SAMARIUM(+3)NITRATE HEXAHYDRATE
SAMARIUM (III) NITRATE
SAMARIUM(III) NITRATE HEXAHYDRATE
SAMARIUM NITRATE HEXAHYDRATE
nitricacid,samarium(3+)salt,hexahydrate
samarium(iii)nitrate,hexahydrate(1:3:6)
samariumnitrat
samariumtrinitratehexahydrate
Samarium(III) nitrate hexahydrate, 99.999% metals basis
SAMARIUM(III) NITRATE HEXAHYDRATE, 99.9%
SAMARIUM (III) NITRATE, REACTON, 99.99% (REO)
SAMARIUM (III) NITRATE HEXAHYDRATE (99.9%-SM) (REO)
Samarium(III) nitrate hexahydrate, 99.90%
samarium(iii) nitrate hydrate, reacton
Samarium(III) nitrate hydrate, REacton(R), 99.99% (REO)
Trinitric acid samarium(III)·6hydrate | [EINECS(EC#)]
233-798-6 | [Molecular Formula]
H12N3O15Sm | [MDL Number]
MFCD00149857 | [Molecular Weight]
444.47 | [MOL File]
13759-83-6.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow crystals or crystalline powder | [Melting point ]
78°C | [density ]
2.375 | [storage temp. ]
0-6°C
| [solubility ]
H2O: 0.1 g/mL, clear
| [form ]
Crystals or Crystalline Powder | [color ]
Yellow | [Water Solubility ]
Soluble in water and acetonitrile. | [Sensitive ]
Hygroscopic | [Stability:]
hygroscopic | [InChI]
InChI=1S/3NO3.6H2O.Sm/c3*2-1(3)4;;;;;;;/h;;;6*1H2;/q3*-1;;;;;;;+3 | [InChIKey]
HDCOFJGRHQAIPE-UHFFFAOYSA-N | [SMILES]
[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.O.O.O.O.O.O.[Sm+3] | [CAS DataBase Reference]
13759-83-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
O,Xi | [Risk Statements ]
R8:Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S24/25:Avoid contact with skin and eyes .
S22:Do not breathe dust . | [RIDADR ]
UN 1477 5.1/PG 3
| [WGK Germany ]
2
| [RTECS ]
VP3150000
| [TSCA ]
Yes | [HazardClass ]
5.1 | [PackingGroup ]
III | [HS Code ]
28469099 | [Storage Class]
5.1B - Oxidizing hazardous materials | [Hazard Classifications]
Eye Irrit. 2
Ox. Sol. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
Samarium (III) nitrate hexahydrate is a yellow to tan powder and chunks in physical appearance and is an oxidiser. It has application as a chemical reagent. It is hygroscopic – absorbs moisture from the air.
| [Uses]
Samarium(III) nitrate hexahydrate is a Lewis acid catalyst that is used in the synthesis of a variety of materials for applications such as:
- synthesis of nitrate precursor solution which can be used as a nanocatalyst in the solid oxide regenerative fuel cells.
- for the formation of coumarin derivative by von Pechmann condensation of phenol with ethyl acetoacetate in the presence of samarium complex as catalyst.
- for the preparation of samarium doped ceria, which can be used in the fabrication of electrolyte for fuel cells.
| [Uses]
Samarium(III) nitrate hydrate is used as a catalyst in von Pechmann condensation for the preparation of coumarins. Further, it finds use in optical glasses, structural ceramics, catalysts, electrical components and photo-optical material. It is also used as a laboratory reagent. In addition to this, it is used in NMR spectroscopy for spectral resolution and is used for doping purposes. | [reaction suitability]
reagent type: catalyst
core: samarium |
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