ChemicalBook--->CAS DataBase List--->1380314-24-8

1380314-24-8

1380314-24-8 Structure

1380314-24-8 Structure
IdentificationBack Directory
[Name]

-
[CAS]

1380314-24-8
[Synonyms]

Chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]-{[1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]-2H-imidazol-2-ylidene}palladium(II), min. 97%
[Molecular Formula]

C78H65ClN2Pd
[MDL Number]

MFCD28411650
[MOL File]

1380314-24-8.mol
[Molecular Weight]

1171.25
Chemical PropertiesBack Directory
[Melting point ]

>300°C
[form ]

Powder
[color ]

yellow
[InChIKey]

CEGNVDTVPMGIJR-UHFFFAOYSA-N
[SMILES]

[Pd].Cl.N7(CN(C=C7)c8c(cc(cc8C(c%12ccccc%12)c%11ccccc%11)C)C(c%10ccccc%10)c9ccccc9)c2c(cc(cc2C(c6ccccc6)c5ccccc5)C)C(c4ccccc4)c3ccccc3.C(Cc1ccccc1)C
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H413-H302+H312+H332-H319-H315
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

CX33, also known as Chlorophenylallyl[1,3-bis(2,6-diphenylmethyl)-4-methylphenyl-2-imidazolylidene]palladium(II), is a homogeneous catalyst useful for cross coupling reactions with arenes, arylation, Buchwald-Hartwig amination, and Suzuki-Miyaura coupling reactions.
[Reactions]

  1. Buchwald-Hartwig cross-coupling of aryl compounds.
  2. Preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling.
  3. Direct S-arylation of unactivated arylsulfoxides.
Reactions of 1380314-24-8
[reaction suitability]

reagent type: catalyst
reaction type: Cross Couplings
[storage]

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
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