ChemicalBook--->CAS DataBase List--->13826-83-0

13826-83-0

13826-83-0 Structure

13826-83-0 Structure
IdentificationMore
[Name]

Ammonium fluoborate
[CAS]

13826-83-0
[Synonyms]

AMMONIUM BOROFLUORIDE
AMMONIUM FLUOBORATE
AMMONIUM FLUOROBORATE
AMMONIUM TETRAFLUOROBORATE
ammoniumfluoroborate[qr]
ammoniumtetrafluoroborate(1-)
ammoniumtetrafluoroborate(1-)[qr]
ammoniumtetrafluoroborate[qr]
Borate(1-),tetrafluoro-,ammonium
tetrafluoro-borate(1-ammonium
tetrafluoro-borate(1-ammonium[qr]
Ammonium tetrafluoroborate
Ammonium fluoborate
Ammonium tetrafluoroborate, 99.999% metals basis
Ammonium tetrafluoroborate, 99.99% metals basis
AMMONIUM TETRAFLUOROBORATE, 97+%
Ammonium tetrafluoroborate, pure
AMMONIUM TETRAFLUOROBORATE 99.99+%
Ammoniumtetrafluoroborate,99%
AMMONIUMFLUOBORATE,CRYSTAL,TECHNICAL
Ammonium tetrafluoroborate 98%
[EINECS(EC#)]

237-531-4
[Molecular Formula]

BF4H4N
[MDL Number]

MFCD06245785
[Molecular Weight]

104.84
[MOL File]

13826-83-0.mol
Chemical PropertiesBack Directory
[Appearance]

white crystalline powder
[Melting point ]

230 °C
[density ]

1.871 g/mL at 25 °C(lit.)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

White
[Specific Gravity]

1.871
[PH]

3.5 (5g/l, H2O, 20℃)
[Water Solubility ]

soluble
[Sensitive ]

Moisture Sensitive
[Exposure limits]

ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
[InChI]

InChI=1S/BF4.H3N/c2-1(3,4)5;/h;1H3/q-1;/p+1
[InChIKey]

PDTKOBRZPAIMRD-UHFFFAOYSA-O
[SMILES]

F[B-](F)(F)F.[NH4+]
[CAS DataBase Reference]

13826-83-0(CAS DataBase Reference)
[EPA Substance Registry System]

13826-83-0(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

C
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN 9088
[WGK Germany ]

3
[RTECS ]

BQ6100000
[Hazard Note ]

Corrosive/Moisture Sensitive
[TSCA ]

T
[REACH Registrations]

Active
[HazardClass ]

8
[HazardClass ]

MOISTURE SENSITIVE, CORROSIVE
[HS Code ]

28269090
[Storage Class]

8B - Non-combustible corrosive hazardous materials
[Hazard Classifications]

Skin Corr. 1B
[Safety Profile]

A poison and strong irritant. See also FLUORIDES and BORON COMPOUNDS. When heated to decomposition it emits very toxic fumes of F-, NO,, and NH3.
[Hazardous Substances Data]

13826-83-0(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ammonia-->Hydrogen fluoride-->Ammonium bicarbonate-->Fluoroboric acid-->Boric acid-->Hexafluorosilicic acid-->Flow Cell
[Preparation Products]

Fluorine fluxing agent-->Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate-->Methyl 1H-indazole-6-carboxylate
Hazard InformationBack Directory
[General Description]

Odorless white crystals. Sinks and mixes with water.
[Reactivity Profile]

Acidic inorganic salts are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
[Air & Water Reactions]

Sublimes above 238°C. to form toxic fumes [AAR 1991]. Water soluble.
[Health Hazard]

INHALATION: May cause irritation of respiratory passages, nose bleeds, and nausea. EYES: May irritate.
[Fire Hazard]

Behavior in Fire: Sublimes above 238°C yielding toxic fumes.
[Chemical Properties]

white crystalline powder
[Uses]

Ammonium fluoroborate is used as an analytical reagent. It is also applied in the textile printing and dyeing industry and used as a catalyst for resin finishing. It is mainly used for the high temperature fluxing action required by the metals industry; catalyst; in flame retardants and acts as a solid lubricant in cutting-oil emulsions for aluminum rolling and forming.
[Synthesis]

Ammonium fluoroborate is obtained by fluorinating boric acid with 40% HF and then neutralizing it with ammonia. It can also be made from ammonium fluoride, boric acid and potassium hydroxide.

Specific steps are:

(1) add 35%-50% potassium h

[Purification Methods]

Crystallise it from conductivity water (1mL/g) between 100o and 0o. 450 Purification of Inorganic Compounds
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Ammonium fluoborate(13826-83-0).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Ammonium fluoborate(13826-83-0)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ammonium tetrafluoroborate, pure(13826-83-0)
[Alfa Aesar]

Ammonium tetrafluoroborate, 99.999% (metals basis)(13826-83-0)
[Sigma Aldrich]

13826-83-0(sigmaaldrich)
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