| Identification | Back Directory | [Name]
4,4',4''-Tris(carbazol-9-yl)-triphenylamine | [CAS]
139092-78-7 | [Synonyms]
TcTa
TCATA
4,4',4''-Tris(carbaz
Tris(4-(9H-carbazol-9-yl)
Tris(4-carbazoyl-9-ylphenyl)amine
Tris[4-(carbazol-9-yl)phenyl]amine
1,3,5-Tris(carbazol-9-ylphenyl)amine
Tris(4-carbazoyl-9-ylphenyl)amine 97%
tris(4-(9H-carbazol-9-yl)phenyl)amine
4,4',4''-Tri-9-carbazolyltriphenylamine
4,4',4''-Tri(9-carbazoyl)triphenylamine
4,4',4''-TRIS(CARBAZOL-9-YL)TRIPHENYLAMINE
4,4',4"-tris(carbazol-9-yl)triphenylaMine/TCTA
TCTA,4,4',4''-Tris(carbazol-9-yl)-triphenylaMine
4-carbazol-9-yl-N,N-bis(4-carbazol-9-ylphenyl)aniline
4,4',4''-Tri-9-carbazolyltriphenylaMine (purified by subliMation)
Benzenamine,4-(9H-carbazol-9-yl)-N,N-bis[4-(9H-carbazol-9-yl)phenyl]- | [EINECS(EC#)]
1312995-182-4 | [Molecular Formula]
C54H36N4 | [MDL Number]
MFCD03093250 | [MOL File]
139092-78-7.mol | [Molecular Weight]
740.89 |
| Chemical Properties | Back Directory | [Melting point ]
298~300°C | [density ]
1.23±0.1 g/cm3(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
THF: soluble
chloroform: soluble
dichloromethane: soluble | [form ]
powder to crystal | [pka]
-5.97±0.60(Predicted) | [color ]
White to Orange to Green | [λmax]
326nm(CH2Cl2)(lit.) | [InChIKey]
AWXGSYPUMWKTBR-UHFFFAOYSA-N | [SMILES]
C1(N(C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)=CC=C(N2C3=C(C=CC=C3)C3=C2C=CC=C3)C=C1 | [CAS DataBase Reference]
139092-78-7 | [Absorption]
λmax?293?and?326 nm (THF) | [Odor]
White powder/crystals |
| Hazard Information | Back Directory | [Chemical Properties]
Light yellow solid | [Description]
Having three carbazole units as the pendants and triarylamine at the core,?tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV). | [Uses]
4,4'',4''''-Tris(carbazol-9-yl)-triphenylamine has been patented for use in the preparation of light-emitting materials for organic electroluminescent devices. |
| Questions And Answer | Back Directory | [Applications]
Having three carbazole units as the pendants and triarylamine at the core, tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV).
TCTA is also a very popular phosphorescent host material due to its large band gap (Eg = 3.4 eV) for green, red and white phosphorescent organic light-emitting diodes (PhOLEDs).
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