ChemicalBook--->CAS DataBase List--->2085-33-8

2085-33-8

2085-33-8 Structure

2085-33-8 Structure
IdentificationMore
[Name]

8-Hydroxyquinoline aluminum salt
[CAS]

2085-33-8
[Synonyms]

8-HYDROXYQUINOLINE, ALUMINUM SALT
8-QUINOLINOL ALUMINUM COMPLEX
ALQ
ALQ3
Aluminium tris(quinolin-8-olate)
ALUMINUM 8-HYDROXYQUINOLINATE
ALUMINUM TRIS(8-HYDROXYQUINOLINATE)
ALUMINUM TRIS(8-QUINOLINATE)
TRIS(8-HYDROXYQUINOLATO) ALUMINUM
TRIS(8-HYDROXYQUINOLINATO)ALUMINIUM
TRIS(8-QUINOLINOLATO)ALUMINUM
Tris(8-hydroxyquinoline)aluminum
8-HYDROXYQUINOLINE, ALUMINUM SALT, 99.99 5%
8-Hydroxyquinoline)aluminiumsalt
Tris(8-hydroxyquinoline)aluminiumsalt
Tri-8-quinolinolatoaluminum
TRIS(8-HYDROXY-CHINOLINATO)ALUMINIUM
Aluminumhydroxyquinolinate
8-HYDROXYQUINOLINE, ALUMINUM SALT 98%
Tris(8-hydroxyquinolinato)alminum(III)
[EINECS(EC#)]

218-227-0
[Molecular Formula]

C27H18AlN3O3
[MDL Number]

MFCD00191693
[Molecular Weight]

459.43
[MOL File]

2085-33-8.mol
Chemical PropertiesBack Directory
[Melting point ]

>300 °C(lit.)
[Boiling point ]

21 °C(Press: 0.16 Torr)
[density ]

1.19 g/cm3
[storage temp. ]

2-8°C, sealed storage, away from moisture
[solubility ]

Solubility in chloroform
[form ]

powder to crystal
[color ]

Light yellow to Amber to Dark green
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[λmax]

259 nm
[Detection Methods]

HPLC
[Merck ]

370
[Exposure limits]

ACGIH: TWA 1 mg/m3
[InChI]

InChI=1S/3C9H7NO.Al/c3*11-8-5-1-3-7-4-2-6-10-9(7)8;/h3*1-6,11H;/q;;;+3/p-3
[InChIKey]

TVIVIEFSHFOWTE-UHFFFAOYSA-K
[SMILES]

C12N=CC=CC=1C=CC=C2O[Al](OC1C=CC=C2C=CC=NC=12)OC1C=CC=C2C=CC=NC=12
[CAS DataBase Reference]

2085-33-8(CAS DataBase Reference)
[Absorption]

λmax 259 nm (in THF)
[Description]

Tris(8-hydroxyquinoline)aluminum(III), commonly known as Alq3, is widely used in organic light-emitting diodes (OLEDs) as an electron-transport material (ETM) and emitting layer material (ELM) due to its high thermal stability, high quantum yield of fluorescence and high electron-transport ability.
[Odor]

Yellow-greenish powder
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

BD2231000
[TSCA ]

No
[HS Code ]

29339900
Questions And AnswerBack Directory
[Classification]

Organometallic, Electron transport-layer materials (ETL), Electron injection-layer materials (EIL), OLED emitting layer material (ELM).
Hazard InformationBack Directory
[Chemical Properties]

Luminous yellow powder
[Uses]

In OLEDs as an electron transport and/or light emitting layer.
[General Description]

Tris(8-hydroxyquinoline)aluminum(III)(Alq3) is a key green-light emitting and electron transport material for OLEDs. A study reports the new crystalline phase d besides its, originally known, three other crystalline phases, α,β,γ. It exhibits excellent chemical stability and high luminescence efficiencies.
[Synthesis]

A new method for the synthesis of aluminum 8-hydroxyquinolines with a short process, low production cost and low pollution:

First step, add material

According to the molar ratio of 8-hydroxyquinoline:aluminum formate=3:1, the reaction m

Spectrum DetailBack Directory
[Spectrum Detail]

8-Hydroxyquinoline aluminum salt(2085-33-8)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

2085-33-8(sigmaaldrich)
[TCI AMERICA]

Tris(8-quinolinolato)aluminum,>98.0%(T)(2085-33-8)
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