ChemicalBook--->CAS DataBase List--->13933-31-8

13933-31-8

13933-31-8 Structure

13933-31-8 Structure
IdentificationMore
[Name]

Sensitizer
[CAS]

13933-31-8
[Synonyms]

TETRAAMMINEPALLADIUM (II) CHLORIDE
TETRAAMMINEPALLADIUM(II) CHLORIDE MONOHYDRATE
Palladium(II) tetrammine chloride
TeTraamminepalladium (II) chloride aq. Soln
TETRAAMMINEPALLADIUM(II) CHLORIDE MONO-H YDRATE, 99.99+%
Tetraamminepalladium(II)chloride,metalsbasis,Pd39%min
PALLADIUM(II) TETRAAMMINE CHLORIDE
Sensitizer
Tetraamminepalladium(II) chloride monohydrate, 99.9% (metals basis), Pd 39% min
Tetraamminepalladium (II) chloride, Premion, 99.999% (metals basis), Pd 43%
Dichlorotetraaminopalladium
[EINECS(EC#)]

604-126-2
[Molecular Formula]

Cl2H14N4OPd
[MDL Number]

MFCD00151033
[Molecular Weight]

263.46
[MOL File]

13933-31-8.mol
Chemical PropertiesBack Directory
[Melting point ]

120 °C (dec.)(lit.)
[density ]

1.91 g/mL at 25 °C(lit.)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder or crystals
[Water Solubility ]

Soluble in water.
[Sensitive ]

Hygroscopic
[InChI]

InChI=1S/2ClH.4H3N.H2O.Pd/h2*1H;4*1H3;1H2;/q;;;;;;;+2/p-2
[InChIKey]

WVCXSPJPERKPJS-UHFFFAOYSA-L
[SMILES]

[Pd](Cl)Cl.N.N.N.N.O
[CAS DataBase Reference]

13933-31-8(CAS DataBase Reference)
[NIST Chemistry Reference]

tetraamminepalladium dichloride(13933-31-8)
Hazard InformationBack Directory
[Chemical Properties]

hygroscopic [ALD94]
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
[Synthesis]

A method for preparing solid crystals of dichlorotetraamminepalladium. Steps include: 1) Dissolving palladium flakes or powder with aqua regia. 2) Removing nitrate by heating with hydrochloric acid. 3) Slowly adding ammonia for complexation to pH=8, then
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

9
Questions and Answers (Q&A)Back Directory
[Uses]

Tetraamminepalladium(II) chloride monohydrate is used to prepare trans-diamminedichloropalladium(II). It is also utilized in the preparation of mesoporous carbon supporting palladium nanoparticles by using graphite oxide. It is used as catalysts, reagents, and analytical reagents.
Spectrum DetailBack Directory
[Spectrum Detail]

Tetraamminepalladium(II) chloride monohydrate(13933-31-8)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Tetraamminepalladium(II) chloride monohydrate, 99.9% (metals basis), Pd 39% min(13933-31-8)
[Sigma Aldrich]

13933-31-8(sigmaaldrich)
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