| Identification | Back Directory | [Name]
TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) | [CAS]
14221-00-2 | [Synonyms]
[(PhO)3P]4Ni
Tetrakis(triphenyl phosphite)nickel
Tetrakis(triphenoxyphosphine)nickel
Nickel tetrakis(triphenoxyphosphine)
TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0)
tetrakis(triphenyl phosphite)nickel(O)
Tetrakis(triphenyl phosphite)nickel(0),95% | [Molecular Formula]
C72H60NiO12P4 | [MDL Number]
MFCD00010007 | [MOL File]
14221-00-2.mol | [Molecular Weight]
1299.83 |
| Chemical Properties | Back Directory | [Appearance]
white to off-white powder | [Melting point ]
145 °C (dec.)(lit.)
| [storage temp. ]
Refrigerator (+4°C) | [solubility ]
sol THF, toluene. | [form ]
solid | [InChI]
InChI=1S/4C18H15O3P.Ni/c4*1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18;/h4*1-15H; | [InChIKey]
PGXCIAAANFTEKX-UHFFFAOYSA-N | [SMILES]
[Ni].O(P(Oc1ccccc1)Oc2ccccc2)c3ccccc3.O(P(Oc4ccccc4)Oc5ccccc5)c6ccccc6.O(P(Oc7ccccc7)Oc8ccccc8)c9ccccc9.O(P(Oc%10ccccc%10)Oc%11ccccc%11)c%12ccccc%12 | [EPA Substance Registry System]
Nickel, tetrakis(triphenyl phosphite-.kappa.P)-, (T-4)- (14221-00-2) |
| Hazard Information | Back Directory | [Chemical Properties]
white to off-white powder | [Uses]
Catalyst for alkene and alkyne hydrocyanation and styrenedimerization | [Preparation]
Tetrakis(triphenyl phosphite)nickel(0) can be prepared by treating Nickel(II) Acetylacetonate with Sodium Borohydride and
Triphenyl Phosphite.[1] | [reaction suitability]
core: nickel
reagent type: catalyst | [storage]
Tetrakis(triphenyl phosphite)nickel(0) is a cancer suspect agent; is air sensitive and should be handled using
Schlenk or glove-box techniques. | [References]
1. McLaughlin, J. R. Inorg. Nucl. Chem. Lett. 1973, 9, 565. |
|
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
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http://www.energy-chemical.com |
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