ChemicalBook--->CAS DataBase List--->14564-35-3

14564-35-3

14564-35-3 Structure

14564-35-3 Structure
IdentificationBack Directory
[Name]

DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
[CAS]

14564-35-3
[Synonyms]

DICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHIN&
Dichlorodicarbonylbis(triphenylphosphine)
dicarbonyldichlorobis(triphenylphosphine)-rutheni
dicarbonyldichlorobis(triphenylphosphine)ruthenium
Dichlorodicarbonylbis-(triphenylphosphino)-ruthenium
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(Ⅱ)
Dichlorocarbonylbis(triphenylphosphine)ruthenium (II)
RUTHENIUM(II)-BIS(TRIPHENYLPHOSPHINE)DICHLOROCARBONYL
DICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICARBONYL CHLORIDE
Dichlorodicarbonylbis(triphenylphosphine)rutheniuM(II),97%
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II),min.98%
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), min. 98%
Dichloro-dicarbonyl-bis(triphenylphosphine) RutheniuM (II) Chloride
Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride >=98.0% (CH)
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), Ruthenium(II)bis(triphenylphosphine)dichlorocarbonyl
[EINECS(EC#)]

238-605-9
[Molecular Formula]

C38H30Cl2O2P2Ru
[MDL Number]

MFCD00009594
[MOL File]

14564-35-3.mol
[Molecular Weight]

752.57
Chemical PropertiesBack Directory
[Appearance]

white crystals
[Melting point ]

230-235°C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

white
[InChI]

InChI=1S/2C18H15P.2CO.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;;;/h2*1-15H;;;2*1H;/q;;;;;;+2/p-2
[InChIKey]

PXURRFCLQDNZOY-UHFFFAOYSA-L
[SMILES]

P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.[Ru](Cl)Cl.[O+]#[C-].[O+]#[C-]
[CAS DataBase Reference]

14564-35-3
[EPA Substance Registry System]

Ruthenium, dicarbonyldichlorobis(triphenylphosphine)- (14564-35-3)
Questions And AnswerBack Directory
[Uses]

Dichlorodicarbonylbis(triphenylphosphine)ruthenium exhibits good catalytic performance in the addition reaction of aromatic ketone carbonyl groups with olefin molecules, and can be widely used as a noble metal catalyst in organic synthesis reactions.
Hazard InformationBack Directory
[Chemical Properties]

white crystals
[reaction suitability]

core: ruthenium
reagent type: catalyst
[Synthesis]

A certain amount of triphenylphosphine was weighed and added to a 100mL three-necked flask having a quantitative anhydrous ethanol solution, stirred, and heated to boiling, then a certain amount of ruthenium trichloride trihydrate, formaldehyde solution,
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HS Code ]

28439090
[Storage Class]

11 - Combustible Solids
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