| Identification | Back Directory | [Name]
Carbonylchlorohydrotris(triphenylphosphine)ruthenium | [CAS]
16971-33-8 | [Synonyms]
carbonylchlorohydridotris(triphenyl-phosphine)rut
Carbonylchlorohydrido tris (triphenylphosphine) ru
carbonylchlorohydrotris(triphenylphosphine)ruthenium
Carbonylchlorohydridotris(triphenylphosphine)ruthenium
Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99%
Carbonylchlorohydridotris(triphenylphosphine)rutheniuM(II),98% (PPh3)3(CO)HRuCl | [EINECS(EC#)]
241-051-0 | [Molecular Formula]
C55H45ClOP3Ru | [MDL Number]
MFCD00049804 | [MOL File]
16971-33-8.mol | [Molecular Weight]
951.39 |
| Chemical Properties | Back Directory | [Appearance]
pale yellow crystals | [Melting point ]
204-206 °C (dec.)(lit.)
| [Boiling point ]
approximate 360℃ | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
Powder | [color ]
Cream to tan | [Water Solubility ]
insoluble | [Sensitive ]
Air stable, light sensitive | [InChI]
InChI=1S/3C18H15P.CO.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;1H;/q;;;;;+1/p-1 | [InChIKey]
MVJRXTSUBHUUPN-UHFFFAOYSA-M | [SMILES]
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.Cl[Ru].[O+]#[C-] |
| Hazard Information | Back Directory | [Chemical Properties]
pale yellow crystals | [Uses]
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR). | [reaction suitability]
core: ruthenium
reagent type: catalyst |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
- Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
- Catalyst for amination of alcohols with ammonia.
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J & K SCIENTIFIC LTD.
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Alfa Aesar
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Energy Chemical
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Jia Xing Isenchem Co.,Ltd
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