ChemicalBook--->CAS DataBase List--->14593-46-5

14593-46-5

14593-46-5 Structure

14593-46-5 Structure
IdentificationMore
[Name]

Sodium tert-pentoxide
[CAS]

14593-46-5
[Synonyms]

SODIUM 2-METHYL-2-BUTOXIDE
SODIUM T-AMYLATE
SODIUM TERT-AMOXIDE
SODIUMTERT-AMYL ALCOHOL
SODIUM TERT-PENTOXIDE
SODIUM TEXT-PENTOXIDE
SODIUM T-PENTYLOXIDE
STA
2-methyl-2-butanosodiumsalt
sodiumt-amylate,sta
sodiumt-amylate,sta,in
sodiumt-amylate,sta,inhexanes
sodiumt-amylate,sta,int-amylalcohol
sodiumt-amylate,sta,intetrahydrofuran
sodiumt-amylate,sta,intoluene
sodium 2-methylbutan-2-olate
Sodium t-amylate, in hexanes
Sodium t-amylate, in t-amyl alcohol
Sodium t-amylate, in tetrahydrofuran
Sodium t-amylate, in toluene
[EINECS(EC#)]

238-639-4
[Molecular Formula]

C5H11NaO
[MDL Number]

MFCD00064245
[Molecular Weight]

110.13
[MOL File]

14593-46-5.mol
Chemical PropertiesBack Directory
[Appearance]

Cream or light tan powder
[Melting point ]

200°C
[density ]

0.904 g/mL at 25 °C
[vapor pressure ]

0-0Pa at 20-50℃
[refractive index ]

n20/D1.415
[Fp ]

-21 °C
[storage temp. ]

Flammables + water-Freezer (-20°C)e area
[form ]

Powder
[color ]

Cream or light tan
[Specific Gravity]

0.91
[Water Solubility ]

Reacts with water.
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

3983987
[InChI]

1S/C5H11O.Na/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1
[InChIKey]

CGRKYEALWSRNJS-UHFFFAOYSA-N
[SMILES]

[Na+].CCC(C)(C)[O-]
[CAS DataBase Reference]

14593-46-5(CAS DataBase Reference)
[EPA Substance Registry System]

14593-46-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H261-H290-H304-H314-H332-H335-H336-H361d-H373-H412
[Precautionary statements ]

P210-P231+P232-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

F,C
[Risk Statements ]

R11:Highly Flammable.
R14/15:Reacts violently with water, liberating extremely flammable gases .
R35:Causes severe burns.
R14:Reacts violently with water.
[Safety Statements ]

S6:Keep under ... (inert gas to be specified by the manufacturer) .
S22:Do not breathe dust .
S33:Take precautionary measures against static discharges .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S7/8:Keep container tightly closed and dry .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 3206 4.2/PG 2
[WGK Germany ]

1
[F ]

10-21
[TSCA ]

No
[REACH Registrations]

Active
[HazardClass ]

4.1
[PackingGroup ]

II
[HS Code ]

29051990
[Storage Class]

4.2 - Pyrophoric and self-heating hazardous materials
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Eye Dam. 1
Flam. Sol. 1
Self-heat. 1
Skin Corr. 1B
STOT SE 3
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Sodium tert-pentoxide(14593-46-5).msds
Hazard InformationBack Directory
[Chemical Properties]

Cream or light tan powder
[Uses]

Sodium tert-pentyloxide is a effective base for the alkylation of ketones.
[Chemical Reactivity]

Sodium tert-pentoxide is a strong, non-nucleophilic base. It is flammable and moisture sensitive and it is similar in reactivity to the more common potassium tert-butoxide. 
Spectrum DetailBack Directory
[Spectrum Detail]

Sodium tert-pentoxide(14593-46-5)1HNMR
Sodium tert-pentoxide(14593-46-5)IR
Sodium tert-pentoxide(14593-46-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Sodium tert-pentoxide, pure, 95%(14593-46-5)
[Alfa Aesar]

Sodium tert-pentyloxide, 95%(14593-46-5)
[Sigma Aldrich]

14593-46-5(sigmaaldrich)
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