| Identification | More | [Name]
4-Isopropoxylphenylboronic acid | [CAS]
153624-46-5 | [Synonyms]
4-ISOPROPOXYBENZENEBORONIC ACID
4-ISOPROPOXYLPHENYLBORONIC ACID
4-ISOPROPOXYPHENYLBORONIC ACID
AKOS BRN-0675
CHEMBRDG-BB 4009733
P-ISOPROPOXYPHENYLBORONIC ACID
4-Isopropoxyphebylboronic acid
4-Isopropoxyphenylboronic
4-isopropyloxyphenyl-boronic acid
4-ISOPROPOXYPHENOL BORONIC ACID
4-Isopropoxyphenylboronic acid ,97% | [Molecular Formula]
C9H13BO3 | [MDL Number]
MFCD03427051 | [Molecular Weight]
180.01 | [MOL File]
153624-46-5.mol |
| Chemical Properties | Back Directory | [Appearance]
White to off-white or light tan powder | [Melting point ]
150-154°C | [Boiling point ]
321.9±44.0 °C(Predicted) | [density ]
1.10±0.1 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
DMSO (Slightly), Methanol (Slightly) | [form ]
Powder | [pka]
8.78±0.17(Predicted) | [color ]
White to off-white or light tan | [Detection Methods]
HPLC,NMR | [InChI]
1S/C9H13BO3/c1-7(2)13-9-5-3-8(4-6-9)10(11)12/h3-7,11-12H,1-2H3 | [InChIKey]
CJUHQADBFQRIMC-UHFFFAOYSA-N | [SMILES]
CC(C)Oc1ccc(cc1)B(O)O | [CAS DataBase Reference]
153624-46-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HazardClass ]
IRRITANT | [HS Code ]
29319090 | [Storage Class]
13 - Non Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
White to off-white or light tan powder | [Uses]
4-Isopropoxyphenylboronic Acid is used to synthesize potent cytotoxic analogues of the marine alkaloid Lamellarin D. It is also used to synthesize cyclooxygenase-2 (COX-2) inhibitors. | [Uses]
Reactant for:• ;Microwave-mediated click-chemistry synthesis of glyco-porphyrin derivatives with in vitro photo-cytotoxicity for application in photodynamic therapy1• ;Palladium-catalyzed oxidative cross-coupling reactions2• ;Ruthenium-catalyzed hydrogenation reactions3• ;Stereoselective rhodium-catalyzed arylation4• ;Palladium acetate catalyzed C-glycosidation5 | [Uses]
suzuki reaction | [General Description]
Contains varying amounts of anhydride | [Synthesis]
A pentane solution of tert-butyllithium (1.28 M, 51.5 mL, 66.0 mmol) was added dropwise to a solution of 4-isopropoxybromobenzene (5.61 g) in THF (150 ) at -78 °C under an argon atmosphere.
mL) to a solution of 4-isopropoxybromobenzene (5.61 g) in THF (15 |
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