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15521-65-0

15521-65-0 Structure

15521-65-0 Structure
IdentificationMore
[Name]

Nickel bis(dimethyldithiocarbamate)
[CAS]

15521-65-0
[Synonyms]

bis(dimethyldithiocarbamato) nickel complex
METHYL NICLATE
Nickel bis(dimethyldithiocarbamate)
NICKEL DIMETHYLDITHIOCARBAMATE
bis(dimethyldithio-carbamate)nickel
bis(dimethyldithiocarbamato)-nicke
bis(dimethyldithiocarbamato)nickel
dimethyldithiocarbamatonickel
Nickel, bis(dimethylcarbamodithioato-S,S')-, (SP-4-1)-
Nickel, bis(dimethyldithiocarbamato)-
nocracnmc
robacnid.d.
s’)-bis(dimethylcarbamodithioato-(sp-4-1)-nicke
sankel
Nickel-dimethyldithiocarbarmate
Nickel-Dimethyldithiocarbarmate(Ndmc)
Nickel, bis(dimethylcarbamodithioato-.kappa.S,.kappa.S)-, (SP-4-1)-
Bis(dimethyldithiocarbamic acid)nickel(II) salt
[EINECS(EC#)]

239-560-8
[Molecular Formula]

C6H12N2NiS4
[MDL Number]

MFCD00067271
[Molecular Weight]

299.13
[MOL File]

15521-65-0.mol
Chemical PropertiesBack Directory
[Melting point ]

>290°C
[Boiling point ]

488.62°C (estimate)
[density ]

1,77 g/cm3
[Specific Gravity]

1.77
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[CAS DataBase Reference]

15521-65-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Bis(dimethyldithiocarbamato) nickel complex(15521-65-0)
[EPA Substance Registry System]

15521-65-0(EPA Substance)
Safety DataBack Directory
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S22:Do not breathe dust .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[TSCA ]

No
[Toxicity]

LD50 orl-rat: 17 g/kg RCTEA4 45(3),627,72
Hazard InformationBack Directory
[Production Methods]

No proprietary synthesis route for nickel bis(dimethyldithiocarbamate) is available in open literature. However, its production can be inferred from its chemical structure. Its manufacture would follow the standard two step process used for all dimethyldithiocarbamate fungicides: first, dimethyldithiocarbamate salt is generated by reacting dimethylamine with carbon disulfide under alkaline conditions; second, this ligand solution is treated with a soluble nickel(II) salt, typically nickel sulphate or nickel chloride, which causes immediate precipitation of the characteristic light green nickel–dithiocarbamate complex. The solid is then filtered, washed to remove unreacted salts, and dried to yield technical grade material.
[Mechanism of action]

Protective action
[Safety Profile]

Confirmed human carcinogen.Mildly toxic by ingestion.
[Pesticide Type]

Fungicide
Spectrum DetailBack Directory
[Spectrum Detail]

Nickel bis(dimethyldithiocarbamate)(15521-65-0)MS
Nickel bis(dimethyldithiocarbamate)(15521-65-0)IR1
Nickel bis(dimethyldithiocarbamate)(15521-65-0)IR2
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