| Identification | Back Directory | [Name]
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE | [CAS]
155830-69-6 | [Synonyms]
(R)-(-)-[(S)-2-(D
JOSIPHOS SL-J002-1
(R)-(S)-PPF-P(tBu)2
-2-(Diphenylphosphino)
ferrocenyl]ethyldi-tert-butylphosphine
(R)1 (1S)2(DIPHENYLPHOSPHINO)FERROCENYL&
(R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph
-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-(-)-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
(R)-1-1[(S) -2-(Diphenylphospino)ferrocenyl]ethylbis-t-butylphosphine
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
(R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DIPHENYLPHOSPHINO)FERROCENE
(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 97+%
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%
(R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ,97%
(R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, 95+%
(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97%
(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
(R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, 95+% 500MG
(r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-(diphenylphosphino)ferrocene (acc to cas)
Ferrocene, 1-[(1R)-1-[bis(1,1-diMethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-, (2R)-
(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG
Josiphos SL-J002-1, (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS) | [Molecular Formula]
C32H40FeP2 10* | [MDL Number]
MFCD01074442 | [MOL File]
155830-69-6.mol | [Molecular Weight]
542.45 |
| Chemical Properties | Back Directory | [Appearance]
Orange powder | [Melting point ]
218-220°C (dec.) | [alpha ]
-412° ±15° (c 0.5, CHCl3) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
Powder | [color ]
Orange | [InChI]
InChI=1/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/s3 | [InChIKey]
STAGMXYQPGLLTD-MGIYCFTINA-N | [SMILES]
P(C1=CC=CC=C1)(C1=CC=CC=C1)[C]1[CH][CH][CH][C]1[C@@H](C)P(C(C)(C)C)C(C)(C)C.[CH]1[CH][CH][CH][CH]1.[Fe] |&1:18,r,^1:13,14,15,16,17,29,30,31,32,33| |
| Hazard Information | Back Directory | [Chemical Properties]
Orange powder | [Uses]
It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester. | [General Description]
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand. | [Synthesis]
(1) Synthesis of (R)-1-ferrocenyl ethyl di-tert-butylphosphine
Under argon protection, vinyl ferrocene (1 mol, 212 g), (R)-3,3'-bis(3,5-dimethylphenyl)-1,1'-binaphthol phosphonate (0.01 mol, 5.6g) and 1L of toluene, then add di-tert-butylphosphine |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for Palladium-catalyzed amination of aryl halides
- Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
- Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
- Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
- Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
- Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
- Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
- Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
- Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
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J & K SCIENTIFIC LTD.
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Energy Chemical
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Jia Xing Isenchem Co.,Ltd
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