| Identification | Back Directory | [Name]
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE | [CAS]
158923-11-6 | [Synonyms]
JOSIPHOS SL-J009-1
(R)-(S)-cy2PF-PtBu2
(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine
(R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine
(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
(R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DICYCLOHEXYLPHOSPHINO)FERROCENE
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97%
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] ethyldi-t-butylphosphine, min. 97%
(r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to cas)
Ferrocene,1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)-,(2R)- | [EINECS(EC#)]
238-086-9 | [Molecular Formula]
C32H52FeP2 10* | [MDL Number]
MFCD03426994 | [MOL File]
158923-11-6.mol | [Molecular Weight]
554.55 |
| Chemical Properties | Back Directory | [Melting point ]
118-120oC | [alpha ]
-185° ±10° (c 0.5, CHCl3) | [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Chloroform (Slightly), Methanol (Very Slightly) | [form ]
Powder | [color ]
orange | [InChIKey]
FFFWTQLOUUWUJJ-MGIYCFTINA-N | [SMILES]
[Fe].[CH]1[CH][CH][C](P(C2CCCCC2)C2CCCCC2)[C]1[C@H](P(C(C)(C)C)C(C)(C)C)C.[CH]1[CH][CH][CH][CH]1 |&1:19,r,^1:1,2,3,4,18,30,31,32,33,34| |
| Hazard Information | Back Directory | [Chemical Properties]
Orange powder | [Uses]
It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates. | [General Description]
sold in collaboration with Solvias AG | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for Palladium-catalyzed C-N cross-coupling.
- Ligand for Palladium-catalyzed C-S cross-coupling.
- Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
- Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
- Ligand for Palladium-catalyzed C-O cross-coupling.
- Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
- Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation
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