ChemicalBook--->CAS DataBase List--->157859-20-6

157859-20-6

157859-20-6 Structure

157859-20-6 Structure
IdentificationBack Directory
[Name]

TRIISOPROPYLSILYL ACRYLATE
[CAS]

157859-20-6
[Synonyms]

TISA
TIPSA
DK562
DK095
ized with BHT)
Co-Formula CFS-206
TRIISOPROPYLSILYL ACRYLATE
ACRYLOXYTRIISOPROPYLSILANE
TRIS(ISOPROPYL)SILYL ACRYLATE
Propyloxy triisopropyl silane
Triisopropylsilyl acrylate(TISA)
ri(propan-2-yl)silylprop-2-enoate
TIPX(Triisopropyl silyl acrylate)
Tri(propan-2-yl)silyl prop-2-enoate
Acrylic Acid Triisopropylsilyl Ester
Tris(1-methylethyl)silyl 2-propenoate
Acrylic acid trisisopropylsilyl ester
2-Propenoic acid,tris(1-methylethyl)silyl ester
Triisopropylsilyl Acrylate (stabilized with BHT)
[EINECS(EC#)]

457-670-6
[Molecular Formula]

C12H24O2Si
[MDL Number]

MFCD01861733
[MOL File]

157859-20-6.mol
[Molecular Weight]

228.4
Chemical PropertiesBack Directory
[Boiling point ]

230.7±9.0 °C(Predicted)
[density ]

0.91
[vapor pressure ]

4-380Pa at 20-25℃
[refractive index ]

1.4485
[Fp ]

78°
[storage temp. ]

Sealed in dry,2-8°C
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

0.910
[Water Solubility ]

60-1000000mg/L at 20-25℃
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[InChI]

InChI=1S/C12H24O2Si/c1-8-12(13)14-15(9(2)3,10(4)5)11(6)7/h8-11H,1H2,2-7H3
[InChIKey]

PQSIXYSSKXAOFE-UHFFFAOYSA-N
[SMILES]

C(O[Si](C(C)C)(C(C)C)C(C)C)(=O)C=C
[LogP]

-2.3-3.9 at 20-25℃
Safety DataBack Directory
[RIDADR ]

UN3082
[HS Code ]

2931.90.9010
[HazardClass ]

9
Hazard InformationBack Directory
[Chemical Properties]

Colorless Transparent Liquid
[Uses]

Triisopropylsilyl acrylate is a resin monomer used to make new antifouling coatings for marine vessels.
[Preparation]

Stir at the band of 1000ml, in the there-necked flask device of nitrogen mouth and drain, under nitrogen protection, choose triisopropyl silanol, toluene and triethylamine, proportionally 1mol: 400ml: 1.2mol mixes, heating under temperature 45 degree, reacts 3 hours; Add thiodiphenylamine, the quality of thiodiphenylamine is 0.03% of triisopropyl silanol quality; Add acrylate chloride, the ratio of acrylate chloride and triisopropyl silanol is 1mol: 1.2mol; React 2 as a child rectifying and draw Triisopropylsilyl acrylate, after measured, the rate of recovery of product is 97%, and purity is greater than 99.7%.
[Flammability and Explosibility]

Notclassified
[References]

[1] Fereshteh K. Yousefi. “Terpolymerization of Triisopropylsilyl Acrylate, Methyl Methacrylate, and Butyl Acrylate: Reactivity Ratio Estimation.” Macromolecular Reaction Engineering 13 4 (2019).
Spectrum DetailBack Directory
[Spectrum Detail]

Triisopropylsilyl acrylate(157859-20-6)1HNMR
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