| Identification | Back Directory | [Name]
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) | [CAS]
1621274-17-6 | [Synonyms]
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-met...
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
(SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium | [Molecular Formula]
C48H35FeNO3P2PdS | [MDL Number]
MFCD30718058 | [MOL File]
1621274-17-6.mol | [Molecular Weight]
930.08 |
| Chemical Properties | Back Directory | [Melting point ]
201 °C | [storage temp. ]
-20°C | [form ]
powder | [Appearance]
Orange to reddish brown Solid | [SMILES]
CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.[C]3(P(C4=CC=CC=C4)C5=CC=CC=C5)[C][C][C][C]3.[C]6(P(C7=CC=CC=C7)C8=CC=CC=C8)[C][C][C][C]6.[Fe] |
| Hazard Information | Back Directory | [Uses]
DPPF Pd G4 is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings |
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