| Identification | Back Directory | [Name]
Palladacycle Gen. 3 | [CAS]
1447963-73-6 | [Synonyms]
Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98% | [Molecular Formula]
C41H54N3O3PPdS | [MOL File]
1447963-73-6.mol | [Molecular Weight]
806.35 |
| Chemical Properties | Back Directory | [Melting point ]
176-178 °C (decomposition) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
Powder | [color ]
white to off-white | [InChIKey]
BYZMMBLECCTRMT-UHFFFAOYSA-N | [SMILES]
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1N(C)C)N(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C |
| Questions and Answers (Q&A) | Back Directory | [Reactions]
- Catalyst for the highly selective cross-coupling of secondary alkylzinc reagents with heteroaryl halides
- Catalyst for the completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles
|
| Hazard Information | Back Directory | [Uses]
CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions. | [General Description]
CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings |
|
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
LaaJoo
|
| Telephone: |
021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
|