ChemicalBook--->CAS DataBase List--->16219-75-3

16219-75-3

16219-75-3 Structure

16219-75-3 Structure
IdentificationMore
[Name]

5-ETHYLIDENE-2-NORBORNENE
[CAS]

16219-75-3
[Synonyms]

5-ETHYLIDENE-2-NORBORNENE
ETHYLIDENE-2-NORBORNENE
ETHYLIDENE NORBORNENE
(5E)-5-Ethylidenebicyclo[2.2.1]hept-2-ene
2-Norbornene, 5-ethylidene-
2-norbornene,5-ethylidene-
5-Ethylidene bicyclo[2,2,1]heptene
5-ethylidene-2-norbornen
5-ethylidene-2-norbornene,mixt.ofendo-andexo-isomers
5-ethylidenebicyclo(2,2,1)hep-2-ene
5-ethylidene-bicyclo(2.2.1)hept-2-en
5-ethylidenebicyclo(2.2.1)hept-2-ene
5-Ethylidenebicyclo[2,2,1]hept-2-nen
5-Ethylidenebicyclo[2.2.1]-2-heptene
5-ethylidene-bicyclo[2.2.1]hept-2-en
5-ethylidene-Bicyclo[2.2.1]hept-2-ene
5-Ethylidenebicyclo[2.2.1]hept-2-ene
bicyclo[2.2.1]hept-2-ene,5-ethylidene-
enb
mixcis+trans-5-ethylidenebicyclo[2.2.1]hept-2-ene
[EINECS(EC#)]

240-347-7
[Molecular Formula]

C9H12
[MDL Number]

MFCD00167576
[Molecular Weight]

120.19
[MOL File]

16219-75-3.mol
Chemical PropertiesBack Directory
[Definition]

A diene used as the third monomer in EPDM elastomers.
[Appearance]

5-Ethylidene- 2-norbornene is a colorless liquid with a turpentine-like odor. The Odor Threshold is 0.007 ppm.
[Melting point ]

-80.15°C
[Boiling point ]

146 °C(lit.)
[density ]

0.893 g/mL at 25 °C(lit.)
[vapor density ]

4.1 (vs air)
[vapor pressure ]

4.6 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.49(lit.)
[Fp ]

101 °F
[storage temp. ]

Flammables area
[solubility ]

Chloroform (Slightly), Hexanes (Slightly)
[form ]

Liquid
[color ]

Colorless to Almost colorless
[explosive limit]

~6.4%
[Water Solubility ]

Soluble in water (0.01% at 20C).
[Henry's Law Constant]

7.6×10-5 mol/(m3Pa) at 25℃, HSDB (2015)
[Exposure limits]

ACGIH: TWA 2 ppm; STEL 4 ppm
NIOSH: Ceiling 5 ppm(25 mg/m3)
[Stability:]

Volatile
[InChI]

1S/C9H12/c1-2-8-5-7-3-4-9(8)6-7/h2-4,7,9H,5-6H2,1H3/b8-2+/t7-,9-/m0/s1
[InChIKey]

OJOWICOBYCXEKR-WHZSQGQPSA-N
[SMILES]

C\C=C1/C[C@H]2C[C@@H]1C=C2
[LogP]

3.82 at 20℃
[CAS DataBase Reference]

16219-75-3(CAS DataBase Reference)
[EPA Substance Registry System]

5-Ethylidene-2-norbornene (16219-75-3)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS02,GHS07,GHS08,GHS09
[Signal word ]

Danger
[Hazard statements ]

H226-H304-H315-H332-H373-H411
[Precautionary statements ]

P210-P273-P301+P310+P331-P302+P352-P304+P340+P312-P314
[Hazard Codes ]

Xn
[Risk Statements ]

R10:Flammable.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[OEL]

Ceiling: 5 ppm (25 mg/m3)
[RIDADR ]

UN 2929 6.1/PG 2
[WGK Germany ]

2
[RTECS ]

RB9450000
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29021990
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Inhalation
Aquatic Chronic 2
Asp. Tox. 1
Flam. Liq. 3
Skin Irrit. 2
STOT RE 2 Inhalation
[Safety Profile]

Moderately toxic by ingestion. Mildly toxic by inhalation and sh contact. Human systemic effects by inhalation: conjunctiva, olfactory, and taste changes. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

16219-75-3(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Calcium oxide-->1,3-Butadiene-->1,3-Cyclopentadiene-->Dicyclopentadiene-->Norbornene-->3-Chloro-1-butene
Hazard InformationBack Directory
[General Description]

Colorless liquid with an odor of turpentine. Flash point 101°F. Floats on water.
[Reactivity Profile]

ETHYLIDENE NORBORNENE(16219-75-3) may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.
[Air & Water Reactions]

Flammable. Insoluble in water.
[Hazard]

Toxic.
[Health Hazard]

Inhalation of vapors causes headache, confusion, and respiratory distress. Ingestion causes irritation of entire digestive system. Aspiration causes severe pneumonia. Contact with liquid causes irritation of eyes and skin.
[Potential Exposure]

5-Ethylidene-2-norbornene is used as the third monomer in terpolymer elastomers. Those engaged in the synthesis of pharmaceuticals; pesticides, or in the preparation of specialty resins.
[Fire Hazard]

This chemical is flammable.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.
[Incompatibilities]

May form explosive mixture with air. Reacts violently with strong oxidants. Violent reaction with oxygen and strong oxidizers. May accumulate static electrical charges, and may cause ignition of its vapors. The substance may polymerize. Inhibit peroxide formation with tert-butyl catechol. ENB should be stored in a nitrogen atmosphere since it reacts with oxygen
[Chemical Properties]

5-Ethylidene- 2-norbornene is a colorless liquid with a turpentine-like odor. The Odor Threshold is 0.007 ppm.
[Chemical Properties]

clear colorless to yellow liquid
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
[Uses]

5-Ethylidene-2-norbornene is used as a self healing agent for polymeric composites. It is also used to reinforce multiwalled carbon nanotubes.
[Uses]

As third monomer in EPDM (ethylene- propylene diene monomer)
[Uses]

Ethylidene norbornene is the third monomer in EPDM (ethylene–propylene diene monomer) elastomers.
Spectrum DetailBack Directory
[Spectrum Detail]

5-ETHYLIDENE-2-NORBORNENE(16219-75-3)MS
5-ETHYLIDENE-2-NORBORNENE(16219-75-3)1HNMR
5-ETHYLIDENE-2-NORBORNENE(16219-75-3)IR1
5-ETHYLIDENE-2-NORBORNENE(16219-75-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

5-Ethylidene-2-norbornene, mixt. of endo-and exo-isomers, stabilized, 98+%(16219-75-3)
[Alfa Aesar]

5-Ethylidene-2-norbornene, endo + exo, 98%, stab. with 100ppm 4-tert-butylcatechol(16219-75-3)
[Sigma Aldrich]

16219-75-3(sigmaaldrich)
[TCI AMERICA]

5-Ethylidene-2-norbornene,>98.0%(GC)(16219-75-3)
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