| Identification | More | [Name]
Ammonium hexafluorophosphate | [CAS]
16941-11-0 | [Synonyms]
AMMONIUM HEXAFLUOPHOSPHATE
AMMONIUM HEXAFLUOROPHOSPHATE
AMMONIUM HEXAFLUOROPHOSPHATE (V)
hexafluoro-phosphate(1-ammonium
Phosphate(1-),hexafluoro-,ammonium
AMMONIUM HEXAFLUOROPHOSPHATE, 95+%
Ammonium hexafluorophosphate, 99.99% metals basis
Ammonium fluorophosphate
Ammoniumhexafluorophosphate99.
Ammonium hexafluorophosphate, extra pure, 99.5%
AMMONIUM HEXAFLUOROPHOSPHATE 99.9%
AMMONIUM HEXAFLUOROPHOSPHATE 99.99%
Ammonium hexafluorophosphate 99.8%
AMMONIUM HEXAFLUOROPHOSPHATE: 99.5%
Azanium hexafluorophosphate
Ammonium hexafluorophosphate, 99.5%, extra pure
Ammonium hexafluorophosphate, extra pure | [EINECS(EC#)]
241-009-1 | [Molecular Formula]
F6H4NP | [MDL Number]
MFCD00064642 | [Molecular Weight]
163 | [MOL File]
16941-11-0.mol |
| Chemical Properties | Back Directory | [Appearance]
off-white powder | [Melting point ]
58 °C (lit.) | [density ]
2.18 g/mL at 25 °C(lit.)
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
H2O: 50 mg/mL, clear, colorless
| [form ]
Crystalline Powder or Needles | [color ]
White to beige | [Specific Gravity]
2.180 | [Stability:]
Stable. Incompatible with strong acids. Hygroscopic. Combustion may generate hydrogen fluoride, phosphorus oxides, phosphine or ammonia. | [Water Solubility ]
74.8 g/100 mL (20 ºC) | [Sensitive ]
Hygroscopic | [Merck ]
14,526 | [Cosmetics Ingredients Functions]
BUFFERING | [InChI]
InChI=1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1 | [InChIKey]
NIZXKAYXSNUDOU-UHFFFAOYSA-O | [SMILES]
[NH4+].[P-](F)(F)(F)(F)(F)F | [CAS DataBase Reference]
16941-11-0(CAS DataBase Reference) | [EPA Substance Registry System]
16941-11-0(EPA Substance) |
| Questions And Answer | Back Directory | [Preparation]
Ammonium hexafluorophosphate is obtained by fluorinating ammonium fluoride and phosphorus pentachloride in hydrofluoric acid, or by mixing phosphorus pentachloride with dry ammonium fluoride, heating and cooling, dissolving in water, adding "nitroglycerin" reagent to form a precipitate, washing several times with cold water, then shaking with chloroform and ammonia water, removing "nitroglycerin" by extraction, and evaporating in a water bath. | [Description]
Ammonium hexafluorophophate can be used to for the synthesis of non-aqueous polymer gel electrolytes based on polyethylene oxide (PEO), which show high conductivity above 10-2 S/cm at 25°C.1 It can be used to prepare other hexafluorophosphate.2 It is also used for the synthesis of ruthenium and palladium complexes.3
| [Reference]
- J. P. Sharma, S. S. Sekhon, Highly conductive non aqueous polymer gel electrolytes containing ammonium hexafluorophosphate (NH4PF6), Journal of Materials Science, 2006, vol. 41, pp. 3617-3622
- C. Hiort, P. Lincoln, B. Norden, DAN binding of .DELTA.and .LAMBDA.-[Ru(phen)2DPPZ]2+, Journal of the American Chemical Society, 1993, vol. 115, pp. 3448-3454
- D. Schmollinger, J. Kraft, C. Ewald, T. Ziegler, Synthesis of ruthenium and palladium complexes from glycosylated 2,2′-bipyridine and terpyridine ligands, 2017, vol. 58, pp. 3643-3645
|
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [F ]
3 | [Hazard Note ]
Corrosive/Hygroscopic | [TSCA ]
T | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28269090 | [Storage Class]
8B - Non-combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
off-white powder | [Uses]
Ammonium hexafluorophosphate is used as a preservative. It is used as a starting material in the preparation of other hexafluorophosphates. Further, it is used in synthesis of organometalic compounds, especially rhodicinium hexafluorophosphate, which has inert and non-coordinating counter ion. | [General Description]
Ammonium hexafluorophosphate decomposes on heating before melting. Solubility of ammonium hexafluorophosphate in H2O at 20oC is 74.8% w/v. Additionally, it is very soluble in Me2CO, MeOH, EtOH and MeOAc, and is decomposed by boiling mineral acids. | [Purification Methods]
It crystallises from H2O in square plates and decomposes on heating before melting. Its solublility in H2O at 20o is 74.8% w/v, and it is very soluble in Me2CO, MeOH, EtOH and MeOAc but is decomposed by boiling mineral acids. [Lange & Müller Chem Ber 63 1063 1930, Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 195 1963.] |
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956 |
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