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17096-07-0

17096-07-0 Structure

17096-07-0 Structure
IdentificationMore
[Name]

3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE
[CAS]

17096-07-0
[Synonyms]

3-METHACRYLOXYPROPYLTRIS(TRIMETHYLSILOXY)SILANE
3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE
3-METHACRYLOYLOXYPROPYLTRIS-(TRIMETHYLSILYLOXY)-SILAN
3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILYLOXY)SILANE
3-[TRIS(TRIMETHYLSILOXY)SILYL]PROPYL METHACRYLATE
3-[TRIS(TRIMETHYLSILYLOXY)SILYL]PROPYL METHACRYLATE
METHACRYLIC ACID 3-[TRIS(TRIMETHYLSILYLOXY)SILYL]PROPYL ESTER
METHACRYLOXYPROPYLTRIS(TRIMETHYLSILOXY)SILANE
TRIS(TRIMETHYLSILOXY)-3-METHACRYLOXYPROPYLSILANE
2-Propenoic acid, 2-methyl-, 3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl ester
3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate
Tris(trimethylsiloxy)-3-methacryloxypropylsilane+6%Dimer
Tris(trimethylsiloxy)-3-methacryloxypropylsilane(3-Methacryloxypropyltris(trimethylsiloxy)silane)
Tris(trimethylsiloxy)-3-methacryloxypropylsilane+20%Dimer
3-Methacryloxypropyletris(trimethylsiloxy)silane
METHACRYLOXYPROPYLTRIS(TRIMETHYLSILOXY)SILANE: 80%, CONTAINS 20% SIB1400.0
METHACRYLOXYPROPYLTRIS(TRIMETHYLSILOXY)SILANE: 6% DIMER SIB1400
Tris(trimethylsiloxy)silylpropylmethacrylate
Methacrylic acid 4,4-bis(trimethylsilyloxy)-6,6-dimethyl-5-oxa-4,6-disilaheptane-1-yl ester
Methacrylic acid=3-[tris(trimethylsiloxy)silyl]propyl ester
[EINECS(EC#)]

241-165-0
[Molecular Formula]

C16H38O5Si4
[MDL Number]

MFCD00053871
[Molecular Weight]

422.81
[MOL File]

17096-07-0.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless transparent liquid
[Melting point ]

<0°C
[Boiling point ]

112-115 °C0.2 mm Hg(lit.)
[density ]

0.918 g/mL at 25 °C(lit.)
[vapor pressure ]

<1 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.419(lit.)
[Fp ]

>230 °F
[storage temp. ]

below 5° C
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

0.918
[Water Solubility ]

Immiscible with water.
[BRN ]

1888727
[Cosmetics Ingredients Functions]

FILM FORMING
[InChI]

1S/C16H38O5Si4/c1-15(2)16(17)18-13-12-14-25(19-22(3,4)5,20-23(6,7)8)21-24(9,10)11/h1,12-14H2,2-11H3
[InChIKey]

BESKSSIEODQWBP-UHFFFAOYSA-N
[SMILES]

CC(=C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C
[LogP]

9 at 20℃
[CAS DataBase Reference]

17096-07-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Tris(trimethylsiloxy)-3-methacryloxypropylsilane(17096-07-0)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[F ]

10
[TSCA ]

No
[REACH Registrations]

Active
[HS Code ]

29319090
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Advantages]

3-(Methacryloyloxy)propyltris(trimethylsiloxy)silane is a silane-modified methacrylate characterized by its unique siloxy functional groups, which impart hydrophobicity and thermal stability.
[Chemical Properties]

Colorless transparent liquid
[Uses]

3-(Methacryloyloxy)propyltris(trimethylsiloxy) silane acts as a tetramethylsilane-protected silicate compound utilized for proteomics research. It is also used as a silane coupling agent, silane adhesion promoter, silane hydrophobing agent, silane dispersing agent and silane crosslinking agent. It is also employed as a silane moisture scavenger, polypropylene catalyst, silicate stabilizer, polyurethane endcapper silane, silane drying agent, silane curing agent and silane reinforcer. Further, it serves as a silylating agent, silane reducing agent, silyl building block and synthons in synthetic chemistry.
[Reactions]

3-(Methacryloyloxy)propyltris(trimethylsiloxy)silane forms explosive mixtures with air on intense heating.
[Flammability and Explosibility]

Notclassified
[Synthesis]

Trimethylsilyl acetate

2754-27-0

3-Methacryloxypropyltrimethoxysilane

2530-85-0

3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE

17096-07-0

To a 500 mL three-necked flask equipped with a constant pressure dropping funnel, magnetic stirrer, Dean-Stark splitter and condenser tube, 124.18 g (0.5 mol) of 3-(methacryloyloxy)propyltrimethoxysilane was added under nitrogen protection, followed by 0.15 g of trifluoromethanesulfonic acid and 0.15 g of BHT.A 198.35 g (1.5 mol) of trimethylsilyl acetate was added to the reaction flask by slow dropwise addition through the constant pressure dropping funnel at 80 °C. 198.35 g (1.5 mol) trimethylsilyl acetate to the reaction flask. During the dropwise addition, most of the low-boiling by-products were continuously distilled and collected through a Dean-Stark splitter side tube. After the dropwise addition was completed, stirring of the reaction mixture was continued for 1 hour. The reaction mixture was transferred to a dispensing funnel and washed six times with 100 mL of water until a neutral colorless clear liquid was obtained. A small amount of low-boiling impurities was removed by rotary evaporation under reduced pressure to yield 198.08 g of 3-(1,1,1,5,5,5-hexamethyl-3-((trimethylsilyl)oxy)trisiloxan-3-yl)propyl methacrylate in 93.7% yield.

[References]

[1] Patent: CN103554169, 2016, B. Location in patent: Paragraph 0040-0042
Spectrum DetailBack Directory
[Spectrum Detail]

3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE(17096-07-0)MS
3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE(17096-07-0)1HNMR
3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE(17096-07-0)13CNMR
3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE(17096-07-0)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

3-(Methacryloyloxy)propyltris(trimethylsiloxy)silane, 98%(17096-07-0)
[Sigma Aldrich]

17096-07-0(sigmaaldrich)
[TCI AMERICA]

3-[Tris(trimethylsilyloxy)silyl]propyl Methacrylate,>96.0%(GC)(17096-07-0)
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