ChemicalBook--->CAS DataBase List--->187166-15-0

187166-15-0

187166-15-0 Structure

187166-15-0 Structure
IdentificationBack Directory
[Name]

spinosyn L, 3'-Ethoxy-
[CAS]

187166-15-0
[Synonyms]

Spinetoram L
-Ethoxy Spinosyn L
3'-Ethoxyspinosyn L
3'-Ethoxy Spinosyn L
spinosyn L, 3'-Ethoxy-
Spinetoram L (XDE-175-L)
Spinetoram (minor component)
3‘-Ethoxy Spinosyn L in Acetonitrile
1H-as-Indaceno[3,2-d]oxacyclododecin-7,15-dione, 2-[(6-deoxy-3-O-ethyl-2,4-di-O-methyl-α-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4,14-dimethyl-, (2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS)-
[Molecular Formula]

C43H69NO10
[MOL File]

187166-15-0.mol
[Molecular Weight]

760.009
Chemical PropertiesBack Directory
[Melting point ]

>750C (dec.)
[Boiling point ]

815.3±65.0 °C(Predicted)
[density ]

1.15±0.1 g/cm3(Predicted)
[storage temp. ]

-20°C Freezer, Under inert atmosphere
[solubility ]

Acetonitrile (Slightly), Chloroform (Slightly)
[form ]

Solid
[pka]

8.62±0.60(Predicted)
[color ]

White to Off-White
[EPA Substance Registry System]

1H-as-Indaceno[3,2-d]oxacyclododecin-7,15-dione, 2-[(6-deoxy-3-O-ethyl-2,4-di-O-methyl-.alpha.-L-mannopyranosyl)oxy]-13-[[(2R,5S,6R)-5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl]oxy]-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4,14-dimethyl-, (2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS)- (187166-15-0)
Hazard InformationBack Directory
[Description]

3’-Ethoxy spinosyn L is a minor component of the insecticide spinetoram .
[Uses]

3'-Ethoxyspinosyn L is the minor component in the second generation spinosyn family of bio-insecticides marketed as Spinetoram. 3'-Ethoxyspinosyn L is a semi-synthetic compound prepared by selective ethylation and hydrogenation of Spinosyn L, itself a fermentation product from a biosynthetically blocked mutant of Saccharopolyspora spinosa. As an insecticide, 3'-ethoxyspinosyn L is considered more potent and to have earlier onset and longer duration of action than combinations of spinosyn A and D.
[Uses]

Spinetoram L is an impurity of Spinetoram (S683650), Spinetoram belongs to spinosyn family of insecticides and shows potential of natural products research.
[References]

[1] THOMAS C. SPARKS. Neural network-based QSAR and insecticide discovery: spinetoram[J]. Journal of Computer-Aided Molecular Design, 2008, 22 6-7: 393-401. DOI: 10.1007/s10822-008-9205-8
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