ChemicalBook--->CAS DataBase List--->1878105-23-7

1878105-23-7

1878105-23-7 Structure

1878105-23-7 Structure
IdentificationBack Directory
[Name]

N-XantPhos Pd G4
[CAS]

1878105-23-7
[Synonyms]

C50H42N2O4P2PdS
N-XantPhos Pd G4
(SP-4-4)-[4-(Diphenylphosphino-κP)-6-(diphenylphosphino)-10H-phenoxazine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]palladium
(SP-4-4)-[4-(Diphenylphosphino-κP)-6-(diphenylphosphino)-10H-phenoxazine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]palladium
[Molecular Formula]

C50H42N2O4P2PdS
[MDL Number]

MFCD30718059
[MOL File]

1878105-23-7.mol
[Molecular Weight]

935.32
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C, stored under nitrogen
[form ]

powder or crystals
[Appearance]

Light green to green Solid
[InChIKey]

LQECMIPINHUTAN-UHFFFAOYSA-M
[SMILES]

[MsO][Pd]1C2=CC=CC=C2C3=CC=CC=C3N1C.C4(P(C5=CC=CC=C5)C6=CC=CC=C6)=C(OC(C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C9)=C9N%10)C%10=CC=C4
Safety DataBack Directory
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

N-XantPhos Pd G4 is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.
[reaction suitability]

reagent type: catalyst
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