| Identification | More | [Name]
1,3-PHENYLENEDIACETIC ACID | [CAS]
19806-17-8 | [Synonyms]
1,3-PHENYLENEDIACETIC ACID
M-BENZENEDIACETIC ACID
M-PHENYLENDIACETIC ACID
M-PHENYLENEDIACETIC ACID
RARECHEM AL BO 0129
2,2’-(m-phenylene)di-aceticaci
Benzene-1,3-diacetic acid
m-Phenylendiacetic acid, 97+%
2,2'-(m-phenylene)di-acetic acid
1,3-Benzenebis(acetic acid)
1,3-Benzenebisacetic acid
1,3-Benzenediacetic acid
1,3-Phenylenebisacetic acid | [EINECS(EC#)]
243-332-3 | [Molecular Formula]
C10H10O4 | [MDL Number]
MFCD00004341 | [Molecular Weight]
194.18 | [MOL File]
19806-17-8.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO LIGHT YELLOW FINE CRYSTALLINE POWDER | [Melting point ]
175-177 °C (lit.) | [Boiling point ]
290.62°C (rough estimate) | [density ]
1.2534 (rough estimate) | [refractive index ]
1.5430 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
Fine Crystalline Powder | [pka]
3.93±0.10(Predicted) | [color ]
White to light yellow | [Water Solubility ]
Slightly soluble in water. Solublitiy in methanol is almost transparency. | [BRN ]
2616749 | [InChI]
InChI=1S/C10H10O4/c11-9(12)5-7-2-1-3-8(4-7)6-10(13)14/h1-4H,5-6H2,(H,11,12)(H,13,14) | [InChIKey]
GDYYIJNDPMFMTB-UHFFFAOYSA-N | [SMILES]
C1(CC(O)=O)=CC=CC(CC(O)=O)=C1 | [CAS DataBase Reference]
19806-17-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
AJ2780000
| [HS Code ]
29173990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Toxicity]
mouse,LD50,intravenous,178mg/kg (178mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00636, |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO LIGHT YELLOW FINE CRYSTALLINE POWDER | [Uses]
In order to establish defined biomacromolecular systems for mineralised tissue applications, type I collagen was functionalised with 1,3-phenylenediacetic acid (Ph) and investigated at the molecular, macroscopic and functional levels. The solvothermal reactions of 1,2-bis(imidazol-1?-yl)ethane (bime), 1,3-phenylenediacetic acid, 1,4-phenylenediacetic acid), 1,2-phenylenediacetic acid with different metal ions gave rise to four novel helical coordination polymers. | [Synthesis]
General procedure for the synthesis of 1,3-benzenediacetic acid from 1,3-benzenediacetonitrile: 25 mL of concentrated sulfuric acid was diluted with 35 mL of water, followed by the addition of 24 g of 1,3-benzenediacetonitrile, and the reaction was carried out at reflux for 1 hour and 30 minutes. Upon completion of the reaction, the reaction mixture was poured into 200 mL of ice water and the precipitated crystals were collected by filtration and washed with cold water. Finally, the resulting crystals were dried under reduced pressure at 100 °C for 1 h to give 27 g of 1,3-benzenediacetic acid. | [References]
[1] Organic Process Research and Development, 2011, vol. 15, # 4, p. 871 - 875
[2] Chemische Berichte, 1987, vol. 120, p. 411 - 420
[3] Journal of the Chemical Society, 1932, p. 1477
[4] Journal of the Chemical Society, 1933, p. 1592,1596
[5] Journal fuer Praktische Chemie (Leipzig), 1932, vol. <2> 135, p. 1,4 |
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