ChemicalBook--->CAS DataBase List--->20103-09-7

20103-09-7

20103-09-7 Structure

20103-09-7 Structure
IdentificationMore
[Name]

2,5-Dichlorobenzene-1,4-diamine
[CAS]

20103-09-7
[Synonyms]

1,4-DIAMINO-2,5-DICHLOROBENZENE
2.5-DICHLORO-1.4-BENZENEDIAMINE
2,5-DICHLORO-1,4-PHENYLENEDIAMINE
2,5-DICHLORO-4-PHENYLENEDIAMINE
2,5-dichlorobenzene-1,4-diamine
2,5 DICHLORO PPD
2,5-DICHLORO-P-PHENYLENEDIAMINE
2-CHLORO PPD
AURORA KA-7368
BUTTPARK 100\01-20
1,4-benzenediamine,2,5-dichloro-
1,4-diamino-3,6-dichlorobenzene
2,5-dichlor-1,4-fenylendiamin
2,5-dichlor-1,4-fenylendiamin(czech)
2,5-dichloro-4-benzenediamine
2,5-dichloro-p-phenylenediamin
benzene,2,5-dichloro,1,4-diamino
DICHLORO-PARA-PHENYLENEDIAMINE
DICHLOROPHENYLENEDIAMINE
[EINECS(EC#)]

243-512-1
[Molecular Formula]

C6H6Cl2N2
[MDL Number]

MFCD00007902
[Molecular Weight]

177.03
[MOL File]

20103-09-7.mol
Chemical PropertiesBack Directory
[Appearance]

light brown to pinkish-grey powder
[Melting point ]

164-166 °C (dec.)(lit.)
[Boiling point ]

291.88°C (rough estimate)
[density ]

1.4668 (rough estimate)
[refractive index ]

1.6400 (estimate)
[storage temp. ]

2-8°C
[form ]

powder to crystal
[pka]

3.16±0.10(Predicted)
[color ]

White to Brown
[BRN ]

2803055
[InChI]

InChI=1S/C6H6Cl2N2/c7-3-1-5(9)4(8)2-6(3)10/h1-2H,9-10H2
[InChIKey]

QAYVHDDEMLNVMO-UHFFFAOYSA-N
[SMILES]

C1(N)=CC(Cl)=C(N)C=C1Cl
[CAS DataBase Reference]

20103-09-7(CAS DataBase Reference)
[EPA Substance Registry System]

20103-09-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[WGK Germany ]

3
[RTECS ]

SS9150000
[F ]

9
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29215900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
[Hazardous Substances Data]

20103-09-7(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2,5-Dichloroaniline-->2,5-Dichloro-4-nitroaniline-->1,4-Naphthoquinone-->Hydrazine hydrate-->Water-->Sodium hydroxide
Hazard InformationBack Directory
[Chemical Properties]

light brown to pinkish-grey powder
[Uses]

2,5-Dichlorobenzene-1,4-diamine is used as an intermediate in organic synthesis. In the dye industry, it is used to synthesize the azo pigment Cromophtal Yellow 6G; it can also be used as a raw material for polyurethane synthesis.
[Synthesis]

2,5-DICHLORO-4-NITROANILINE

6627-34-5

1,4-Naphthoquinone

130-15-4

2,5-Dichlorobenzene-1,4-diamine

20103-09-7

Example 2: Add 200 mL of deionized water, 41.4 g of pulverized 2,5-dichloro-4-nitroaniline, 6 g of sodium hydroxide, 0.3 g of 1,4-naphthoquinone, and 25 g of 80% hydrazine hydrate solution to the reaction vessel. The reaction system was kept in an aqueous phase environment. The reaction mixture was stirred continuously for 9 hours at a temperature range of 85°C to 95°C to ensure complete reaction. Upon completion of the reaction, the product was separated by filtration, followed by washing the filter cake with deionized water and drying under appropriate conditions to yield 34.0 g of 2,5-dichloro-1,4-benzenediamine. The purity of the product was determined to be 96% by gas chromatography (G.C.) and the chemical purity analysis resulted in 99.6%.

[References]

[1] Patent: US5041672, 1991, A
[2] Patent: US5041672, 1991, A
Spectrum DetailBack Directory
[Spectrum Detail]

2,5-Dichlorobenzene-1,4-diamine(20103-09-7)MS
2,5-Dichlorobenzene-1,4-diamine(20103-09-7)1HNMR
2,5-Dichlorobenzene-1,4-diamine(20103-09-7)13CNMR
2,5-Dichlorobenzene-1,4-diamine(20103-09-7)IR1
2,5-Dichlorobenzene-1,4-diamine(20103-09-7)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2,5-Dichloro-1,4-phenylenediamine, 99%(20103-09-7)
[Sigma Aldrich]

20103-09-7(sigmaaldrich)
[TCI AMERICA]

2,5-Dichloro-1,4-phenylenediamine,>98.0%(GC)(T)(20103-09-7)
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