| Identification | Back Directory | [Name]
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II) | [CAS]
2049086-35-1 | [Synonyms]
)[(R)-1-[(S)-2-(dicycL
CHLORO(4-CYANOPHENYL){(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYL(DICYCLOHEXYLPHOSPHINE)}NICKEL(II) | [Molecular Formula]
C43H60ClFeNNiP2 | [MDL Number]
MFCD31619174 | [MOL File]
2049086-35-1.mol | [Molecular Weight]
797.86 |
| Chemical Properties | Back Directory | [form ]
solid | [color ]
orange | [SMILES]
Cl[Ni+2]C1=CC=C(C#N)C=C1.C[C@@H](P(C2CCCCC2)C3CCCCC3)[C]4[C][C][C][C]4P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe] |
| Questions And Answer | Back Directory | [Uses]
- Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions.
- Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines.
- Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions.
- Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts.
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